Ecoer Logo

@neverless

25

UNLEASHED CRIME

steemit.com/@neverless
VOTING POWER100.00%
DOWNVOTE POWER100.00%
RESOURCE CREDITS100.00%
REPUTATION PROGRESS0.00%
Net Worth
0.037USD
STEEM
0.001STEEM
SBD
0.005SBD
Effective Power
5.001SP
├── Own SP
0.629SP
└── Incoming Deleg
+4.372SP

Detailed Balance

STEEM
balance
0.001STEEM
market_balance
0.000STEEM
savings_balance
0.000STEEM
reward_steem_balance
0.000STEEM
STEEM POWER
Own SP
0.629SP
Delegated Out
0.000SP
Delegation In
4.372SP
Effective Power
5.001SP
Reward SP (pending)
0.002SP
SBD
sbd_balance
0.000SBD
sbd_conversions
0.000SBD
sbd_market_balance
0.000SBD
savings_sbd_balance
0.000SBD
reward_sbd_balance
0.005SBD
{
  "balance": "0.001 STEEM",
  "savings_balance": "0.000 STEEM",
  "reward_steem_balance": "0.000 STEEM",
  "vesting_shares": "1024.209091 VESTS",
  "delegated_vesting_shares": "0.000000 VESTS",
  "received_vesting_shares": "7119.450715 VESTS",
  "sbd_balance": "0.000 SBD",
  "savings_sbd_balance": "0.000 SBD",
  "reward_sbd_balance": "0.005 SBD",
  "conversions": []
}

Account Info

nameneverless
id580775
rank673,452
reputation110784414
created2018-01-08T13:19:24
recovery_accountsteem
proxyNone
post_count5
comment_count0
lifetime_vote_count0
witnesses_voted_for0
last_post2018-01-08T23:58:18
last_root_post2018-01-08T23:58:18
last_vote_time2018-01-09T12:45:09
proxied_vsf_votes0, 0, 0, 0
can_vote1
voting_power0
delayed_votes0
balance0.001 STEEM
savings_balance0.000 STEEM
sbd_balance0.000 SBD
savings_sbd_balance0.000 SBD
vesting_shares1024.209091 VESTS
delegated_vesting_shares0.000000 VESTS
received_vesting_shares7119.450715 VESTS
reward_vesting_balance4.095361 VESTS
vesting_balance0.000 STEEM
vesting_withdraw_rate0.000000 VESTS
next_vesting_withdrawal1969-12-31T23:59:59
withdrawn0
to_withdraw0
withdraw_routes0
savings_withdraw_requests0
last_account_recovery1970-01-01T00:00:00
reset_accountnull
last_owner_update2018-01-09T14:32:45
last_account_update2018-01-09T14:32:45
minedNo
sbd_seconds0
sbd_last_interest_payment1970-01-01T00:00:00
savings_sbd_last_interest_payment1970-01-01T00:00:00
{
  "id": 580775,
  "name": "neverless",
  "owner": {
    "weight_threshold": 1,
    "account_auths": [],
    "key_auths": [
      [
        "STM6yEWYZVMk3LzBtWQurV5xPhxsjrYgoYUF6ZMz1EyD8wp92NxwJ",
        1
      ]
    ]
  },
  "active": {
    "weight_threshold": 1,
    "account_auths": [],
    "key_auths": [
      [
        "STM6ruFmuqHE6MWErpkVr9USS7BeJB7mQnaJC4DBaJu4rBhzXUSxS",
        1
      ]
    ]
  },
  "posting": {
    "weight_threshold": 1,
    "account_auths": [
      [
        "dtube.app",
        1
      ]
    ],
    "key_auths": [
      [
        "STM6vr4meB9H2SgW1CA4zsdGY243uxXr2jbWAus3x7aqYYtAz9JWe",
        1
      ]
    ]
  },
  "memo_key": "STM7isqcJrnEyaS8rjN7uPtptr1NCrhC3K1yC3XCehYqxkHY5crvb",
  "json_metadata": "{\"profile\":{\"profile_image\":\"http://fs1.directupload.net/images/180108/quwvj2te.jpg\",\"cover_image\":\"http://fs1.directupload.net/images/180108/vzsrxknz.jpg\",\"name\":\"NEVERLESS\",\"about\":\"UNLEASHED CRIME\",\"location\":\"127.0.0.1\"}}",
  "posting_json_metadata": "{\"profile\":{\"profile_image\":\"http://fs1.directupload.net/images/180108/quwvj2te.jpg\",\"cover_image\":\"http://fs1.directupload.net/images/180108/vzsrxknz.jpg\",\"name\":\"NEVERLESS\",\"about\":\"UNLEASHED CRIME\",\"location\":\"127.0.0.1\"}}",
  "proxy": "",
  "last_owner_update": "2018-01-09T14:32:45",
  "last_account_update": "2018-01-09T14:32:45",
  "created": "2018-01-08T13:19:24",
  "mined": false,
  "recovery_account": "steem",
  "last_account_recovery": "1970-01-01T00:00:00",
  "reset_account": "null",
  "comment_count": 0,
  "lifetime_vote_count": 0,
  "post_count": 5,
  "can_vote": true,
  "voting_manabar": {
    "current_mana": "8143659806",
    "last_update_time": 1779078300
  },
  "downvote_manabar": {
    "current_mana": 2035914951,
    "last_update_time": 1779078300
  },
  "voting_power": 0,
  "balance": "0.001 STEEM",
  "savings_balance": "0.000 STEEM",
  "sbd_balance": "0.000 SBD",
  "sbd_seconds": "0",
  "sbd_seconds_last_update": "1970-01-01T00:00:00",
  "sbd_last_interest_payment": "1970-01-01T00:00:00",
  "savings_sbd_balance": "0.000 SBD",
  "savings_sbd_seconds": "0",
  "savings_sbd_seconds_last_update": "1970-01-01T00:00:00",
  "savings_sbd_last_interest_payment": "1970-01-01T00:00:00",
  "savings_withdraw_requests": 0,
  "reward_sbd_balance": "0.005 SBD",
  "reward_steem_balance": "0.000 STEEM",
  "reward_vesting_balance": "4.095361 VESTS",
  "reward_vesting_steem": "0.002 STEEM",
  "vesting_shares": "1024.209091 VESTS",
  "delegated_vesting_shares": "0.000000 VESTS",
  "received_vesting_shares": "7119.450715 VESTS",
  "vesting_withdraw_rate": "0.000000 VESTS",
  "next_vesting_withdrawal": "1969-12-31T23:59:59",
  "withdrawn": 0,
  "to_withdraw": 0,
  "withdraw_routes": 0,
  "curation_rewards": 0,
  "posting_rewards": 3,
  "proxied_vsf_votes": [
    0,
    0,
    0,
    0
  ],
  "witnesses_voted_for": 0,
  "last_post": "2018-01-08T23:58:18",
  "last_root_post": "2018-01-08T23:58:18",
  "last_vote_time": "2018-01-09T12:45:09",
  "post_bandwidth": 0,
  "pending_claimed_accounts": 0,
  "vesting_balance": "0.000 STEEM",
  "reputation": 110784414,
  "transfer_history": [],
  "market_history": [],
  "post_history": [],
  "vote_history": [],
  "other_history": [],
  "witness_votes": [],
  "tags_usage": [],
  "guest_bloggers": [],
  "rank": 673452
}

Withdraw Routes

IncomingOutgoing
Empty
Empty
{
  "incoming": [],
  "outgoing": []
}
From Date
To Date
steemdelegated 4.372 SP to @neverless
2026/05/18 04:25:00
delegatorsteem
delegateeneverless
vesting shares7119.450715 VESTS
Transaction InfoBlock #106148420/Trx 18f4079edbe19695d698a27edcddf80f6bab7a76
View Raw JSON Data
{
  "trx_id": "18f4079edbe19695d698a27edcddf80f6bab7a76",
  "block": 106148420,
  "trx_in_block": 3,
  "op_in_trx": 0,
  "virtual_op": 0,
  "timestamp": "2026-05-18T04:25:00",
  "op": [
    "delegate_vesting_shares",
    {
      "delegator": "steem",
      "delegatee": "neverless",
      "vesting_shares": "7119.450715 VESTS"
    }
  ]
}
steemdelegated 2.706 SP to @neverless
2026/05/12 20:44:00
delegatorsteem
delegateeneverless
vesting shares4407.240310 VESTS
Transaction InfoBlock #105995938/Trx a25883a8b431ecf33f2b488fb5986e3faff5095f
View Raw JSON Data
{
  "trx_id": "a25883a8b431ecf33f2b488fb5986e3faff5095f",
  "block": 105995938,
  "trx_in_block": 2,
  "op_in_trx": 0,
  "virtual_op": 0,
  "timestamp": "2026-05-12T20:44:00",
  "op": [
    "delegate_vesting_shares",
    {
      "delegator": "steem",
      "delegatee": "neverless",
      "vesting_shares": "4407.240310 VESTS"
    }
  ]
}
steemdelegated 4.380 SP to @neverless
2026/04/26 03:39:21
delegatorsteem
delegateeneverless
vesting shares7131.966471 VESTS
Transaction InfoBlock #105515953/Trx 18f9362fdbfc7e806656cdf342fb9f70875a4d52
View Raw JSON Data
{
  "trx_id": "18f9362fdbfc7e806656cdf342fb9f70875a4d52",
  "block": 105515953,
  "trx_in_block": 1,
  "op_in_trx": 0,
  "virtual_op": 0,
  "timestamp": "2026-04-26T03:39:21",
  "op": [
    "delegate_vesting_shares",
    {
      "delegator": "steem",
      "delegatee": "neverless",
      "vesting_shares": "7131.966471 VESTS"
    }
  ]
}
steemdelegated 2.732 SP to @neverless
2026/01/23 18:58:57
delegatorsteem
delegateeneverless
vesting shares4448.787129 VESTS
Transaction InfoBlock #102865207/Trx 64f8e0e7b20a5252e2a704c726706c5a1d5adebb
View Raw JSON Data
{
  "trx_id": "64f8e0e7b20a5252e2a704c726706c5a1d5adebb",
  "block": 102865207,
  "trx_in_block": 3,
  "op_in_trx": 0,
  "virtual_op": 0,
  "timestamp": "2026-01-23T18:58:57",
  "op": [
    "delegate_vesting_shares",
    {
      "delegator": "steem",
      "delegatee": "neverless",
      "vesting_shares": "4448.787129 VESTS"
    }
  ]
}
steemdelegated 2.833 SP to @neverless
2024/12/17 14:10:42
delegatorsteem
delegateeneverless
vesting shares4613.006326 VESTS
Transaction InfoBlock #91311455/Trx 8426369352873c76ecaf270db922d010ca18af2d
View Raw JSON Data
{
  "trx_id": "8426369352873c76ecaf270db922d010ca18af2d",
  "block": 91311455,
  "trx_in_block": 4,
  "op_in_trx": 0,
  "virtual_op": 0,
  "timestamp": "2024-12-17T14:10:42",
  "op": [
    "delegate_vesting_shares",
    {
      "delegator": "steem",
      "delegatee": "neverless",
      "vesting_shares": "4613.006326 VESTS"
    }
  ]
}
steemdelegated 2.937 SP to @neverless
2023/11/14 05:52:21
delegatorsteem
delegateeneverless
vesting shares4782.139858 VESTS
Transaction InfoBlock #79865623/Trx 6c1dbd98c026b97927fcba6ad56975cad7a84559
View Raw JSON Data
{
  "trx_id": "6c1dbd98c026b97927fcba6ad56975cad7a84559",
  "block": 79865623,
  "trx_in_block": 5,
  "op_in_trx": 0,
  "virtual_op": 0,
  "timestamp": "2023-11-14T05:52:21",
  "op": [
    "delegate_vesting_shares",
    {
      "delegator": "steem",
      "delegatee": "neverless",
      "vesting_shares": "4782.139858 VESTS"
    }
  ]
}
steemdelegated 4.740 SP to @neverless
2023/09/22 08:10:09
delegatorsteem
delegateeneverless
vesting shares7719.048644 VESTS
Transaction InfoBlock #78360208/Trx 285f8884bd89d4c3fb2e2c2888699c74ccf302f6
View Raw JSON Data
{
  "trx_id": "285f8884bd89d4c3fb2e2c2888699c74ccf302f6",
  "block": 78360208,
  "trx_in_block": 0,
  "op_in_trx": 0,
  "virtual_op": 0,
  "timestamp": "2023-09-22T08:10:09",
  "op": [
    "delegate_vesting_shares",
    {
      "delegator": "steem",
      "delegatee": "neverless",
      "vesting_shares": "7719.048644 VESTS"
    }
  ]
}
steemdelegated 4.877 SP to @neverless
2022/11/03 15:55:33
delegatorsteem
delegateeneverless
vesting shares7941.100082 VESTS
Transaction InfoBlock #69118303/Trx 425a1d6802afe31fe888883be1b1f94560cbe52d
View Raw JSON Data
{
  "trx_id": "425a1d6802afe31fe888883be1b1f94560cbe52d",
  "block": 69118303,
  "trx_in_block": 1,
  "op_in_trx": 0,
  "virtual_op": 0,
  "timestamp": "2022-11-03T15:55:33",
  "op": [
    "delegate_vesting_shares",
    {
      "delegator": "steem",
      "delegatee": "neverless",
      "vesting_shares": "7941.100082 VESTS"
    }
  ]
}
steemdelegated 5.012 SP to @neverless
2022/01/17 21:18:18
delegatorsteem
delegateeneverless
vesting shares8161.207683 VESTS
Transaction InfoBlock #60821768/Trx 37d1549f9b25bb2fea8155656e312ca2a802f8d9
View Raw JSON Data
{
  "trx_id": "37d1549f9b25bb2fea8155656e312ca2a802f8d9",
  "block": 60821768,
  "trx_in_block": 12,
  "op_in_trx": 0,
  "virtual_op": 0,
  "timestamp": "2022-01-17T21:18:18",
  "op": [
    "delegate_vesting_shares",
    {
      "delegator": "steem",
      "delegatee": "neverless",
      "vesting_shares": "8161.207683 VESTS"
    }
  ]
}
steemdelegated 5.125 SP to @neverless
2021/06/14 04:34:03
delegatorsteem
delegateeneverless
vesting shares8345.401971 VESTS
Transaction InfoBlock #54612198/Trx cfbb83be7274742c8c970a8fbb75249d4b49871a
View Raw JSON Data
{
  "trx_id": "cfbb83be7274742c8c970a8fbb75249d4b49871a",
  "block": 54612198,
  "trx_in_block": 0,
  "op_in_trx": 0,
  "virtual_op": 0,
  "timestamp": "2021-06-14T04:34:03",
  "op": [
    "delegate_vesting_shares",
    {
      "delegator": "steem",
      "delegatee": "neverless",
      "vesting_shares": "8345.401971 VESTS"
    }
  ]
}
steemdelegated 5.240 SP to @neverless
2020/12/11 14:48:06
delegatorsteem
delegateeneverless
vesting shares8532.823945 VESTS
Transaction InfoBlock #49359512/Trx 0b0a8b5dafa9eed07cd11307fae99c45a2844969
View Raw JSON Data
{
  "trx_id": "0b0a8b5dafa9eed07cd11307fae99c45a2844969",
  "block": 49359512,
  "trx_in_block": 1,
  "op_in_trx": 0,
  "virtual_op": 0,
  "timestamp": "2020-12-11T14:48:06",
  "op": [
    "delegate_vesting_shares",
    {
      "delegator": "steem",
      "delegatee": "neverless",
      "vesting_shares": "8532.823945 VESTS"
    }
  ]
}
steemdelegated 1.174 SP to @neverless
2020/12/06 08:24:24
delegatorsteem
delegateeneverless
vesting shares1912.543513 VESTS
Transaction InfoBlock #49211053/Trx f177a8ecccff3bf16477d9e57ba723f0689064d8
View Raw JSON Data
{
  "trx_id": "f177a8ecccff3bf16477d9e57ba723f0689064d8",
  "block": 49211053,
  "trx_in_block": 6,
  "op_in_trx": 0,
  "virtual_op": 0,
  "timestamp": "2020-12-06T08:24:24",
  "op": [
    "delegate_vesting_shares",
    {
      "delegator": "steem",
      "delegatee": "neverless",
      "vesting_shares": "1912.543513 VESTS"
    }
  ]
}
steemdelegated 5.244 SP to @neverless
2020/12/05 18:25:45
delegatorsteem
delegateeneverless
vesting shares8539.031799 VESTS
Transaction InfoBlock #49194597/Trx d8afdfa5bbf146f9adb17eb2aec205105503db34
View Raw JSON Data
{
  "trx_id": "d8afdfa5bbf146f9adb17eb2aec205105503db34",
  "block": 49194597,
  "trx_in_block": 16,
  "op_in_trx": 0,
  "virtual_op": 0,
  "timestamp": "2020-12-05T18:25:45",
  "op": [
    "delegate_vesting_shares",
    {
      "delegator": "steem",
      "delegatee": "neverless",
      "vesting_shares": "8539.031799 VESTS"
    }
  ]
}
steemdelegated 1.179 SP to @neverless
2020/11/02 23:14:42
delegatorsteem
delegateeneverless
vesting shares1920.017158 VESTS
Transaction InfoBlock #48266762/Trx 1c859d206c99079eda66fd2a549340665db544bd
View Raw JSON Data
{
  "trx_id": "1c859d206c99079eda66fd2a549340665db544bd",
  "block": 48266762,
  "trx_in_block": 1,
  "op_in_trx": 0,
  "virtual_op": 0,
  "timestamp": "2020-11-02T23:14:42",
  "op": [
    "delegate_vesting_shares",
    {
      "delegator": "steem",
      "delegatee": "neverless",
      "vesting_shares": "1920.017158 VESTS"
    }
  ]
}
steemdelegated 5.368 SP to @neverless
2020/05/09 09:25:27
delegatorsteem
delegateeneverless
vesting shares8741.837158 VESTS
Transaction InfoBlock #43221353/Trx d28a4403517988317416d19694e903ec18ec4e47
View Raw JSON Data
{
  "trx_id": "d28a4403517988317416d19694e903ec18ec4e47",
  "block": 43221353,
  "trx_in_block": 1,
  "op_in_trx": 0,
  "virtual_op": 0,
  "timestamp": "2020-05-09T09:25:27",
  "op": [
    "delegate_vesting_shares",
    {
      "delegator": "steem",
      "delegatee": "neverless",
      "vesting_shares": "8741.837158 VESTS"
    }
  ]
}
steemdelegated 1.200 SP to @neverless
2020/05/08 13:34:57
delegatorsteem
delegateeneverless
vesting shares1953.311140 VESTS
Transaction InfoBlock #43198102/Trx 2cd5e13d3aea97cb1b6f57abb113be7e5e4e3257
View Raw JSON Data
{
  "trx_id": "2cd5e13d3aea97cb1b6f57abb113be7e5e4e3257",
  "block": 43198102,
  "trx_in_block": 12,
  "op_in_trx": 0,
  "virtual_op": 0,
  "timestamp": "2020-05-08T13:34:57",
  "op": [
    "delegate_vesting_shares",
    {
      "delegator": "steem",
      "delegatee": "neverless",
      "vesting_shares": "1953.311140 VESTS"
    }
  ]
}
steemdelegated 5.376 SP to @neverless
2020/04/16 02:14:12
delegatorsteem
delegateeneverless
vesting shares8754.724606 VESTS
Transaction InfoBlock #42567924/Trx 292aa1bfb75b822d3f1843d24f14a42857b8f6e4
View Raw JSON Data
{
  "trx_id": "292aa1bfb75b822d3f1843d24f14a42857b8f6e4",
  "block": 42567924,
  "trx_in_block": 30,
  "op_in_trx": 0,
  "virtual_op": 0,
  "timestamp": "2020-04-16T02:14:12",
  "op": [
    "delegate_vesting_shares",
    {
      "delegator": "steem",
      "delegatee": "neverless",
      "vesting_shares": "8754.724606 VESTS"
    }
  ]
}
2020/01/08 15:21:48
parent authorneverless
parent permlinkchargeback-paypal
authorsteemitboard
permlinksteemitboard-notify-neverless-20200108t152147000z
title
bodyCongratulations @neverless! You received a personal award! <table><tr><td>https://steemitimages.com/70x70/http://steemitboard.com/@neverless/birthday2.png</td><td>Happy Birthday! - You are on the Steem blockchain for 2 years!</td></tr></table> <sub>_You can view [your badges on your Steem Board](https://steemitboard.com/@neverless) and compare to others on the [Steem Ranking](https://steemitboard.com/ranking/index.php?name=neverless)_</sub> ###### [Vote for @Steemitboard as a witness](https://v2.steemconnect.com/sign/account-witness-vote?witness=steemitboard&approve=1) to get one more award and increased upvotes!
json metadata{"image":["https://steemitboard.com/img/notify.png"]}
Transaction InfoBlock #39751953/Trx 109a9387e50de47a64ed160b686a3bbca7208f00
View Raw JSON Data
{
  "trx_id": "109a9387e50de47a64ed160b686a3bbca7208f00",
  "block": 39751953,
  "trx_in_block": 3,
  "op_in_trx": 0,
  "virtual_op": 0,
  "timestamp": "2020-01-08T15:21:48",
  "op": [
    "comment",
    {
      "parent_author": "neverless",
      "parent_permlink": "chargeback-paypal",
      "author": "steemitboard",
      "permlink": "steemitboard-notify-neverless-20200108t152147000z",
      "title": "",
      "body": "Congratulations @neverless! You received a personal award!\n\n<table><tr><td>https://steemitimages.com/70x70/http://steemitboard.com/@neverless/birthday2.png</td><td>Happy Birthday! - You are on the Steem blockchain for 2 years!</td></tr></table>\n\n<sub>_You can view [your badges on your Steem Board](https://steemitboard.com/@neverless) and compare to others on the [Steem Ranking](https://steemitboard.com/ranking/index.php?name=neverless)_</sub>\n\n\n###### [Vote for @Steemitboard as a witness](https://v2.steemconnect.com/sign/account-witness-vote?witness=steemitboard&approve=1) to get one more award and increased upvotes!",
      "json_metadata": "{\"image\":[\"https://steemitboard.com/img/notify.png\"]}"
    }
  ]
}
dtubesent 0.001 STEEM to @neverless- "Time is running out, claim your DTube account now before anyone else can! Login at https://d.tube"
2019/08/22 16:30:48
fromdtube
toneverless
amount0.001 STEEM
memoTime is running out, claim your DTube account now before anyone else can! Login at https://d.tube
Transaction InfoBlock #35779825/Trx 8fead0c1084453593f58020988da2a8e015b2bd7
View Raw JSON Data
{
  "trx_id": "8fead0c1084453593f58020988da2a8e015b2bd7",
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  "trx_in_block": 14,
  "op_in_trx": 0,
  "virtual_op": 0,
  "timestamp": "2019-08-22T16:30:48",
  "op": [
    "transfer",
    {
      "from": "dtube",
      "to": "neverless",
      "amount": "0.001 STEEM",
      "memo": "Time is running out, claim your DTube account now before anyone else can! Login at https://d.tube"
    }
  ]
}
steemdelegated 5.496 SP to @neverless
2019/05/12 19:20:51
delegatorsteem
delegateeneverless
vesting shares8950.341419 VESTS
Transaction InfoBlock #32850818/Trx 57b137f7c9245e2c7b1b497137a8f7548f3e2258
View Raw JSON Data
{
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  "op_in_trx": 0,
  "virtual_op": 0,
  "timestamp": "2019-05-12T19:20:51",
  "op": [
    "delegate_vesting_shares",
    {
      "delegator": "steem",
      "delegatee": "neverless",
      "vesting_shares": "8950.341419 VESTS"
    }
  ]
}
2019/01/08 15:31:33
parent authorneverless
parent permlinkchargeback-paypal
authorsteemitboard
permlinksteemitboard-notify-neverless-20190108t153132000z
title
bodyCongratulations @neverless! You received a personal award! <table><tr><td>https://steemitimages.com/70x70/http://steemitboard.com/@neverless/birthday1.png</td><td>1 Year on Steemit</td></tr></table> <sub>_[Click here to view your Board](https://steemitboard.com/@neverless)_</sub> **Do not miss the last post from @steemitboard:** <table><tr><td><a href="https://steemit.com/steem/@steemitboard/steemwhales-has-officially-moved-to-steemitboard-ranking"><img src="https://steemitimages.com/64x128/https://cdn.steemitimages.com/DQmfRVpHQhLDhnjDtqck8GPv9NPvNKPfMsDaAFDE1D9Er2Z/header_ranking.png"></a></td><td><a href="https://steemit.com/steem/@steemitboard/steemwhales-has-officially-moved-to-steemitboard-ranking">SteemWhales has officially moved to SteemitBoard Ranking</a></td></tr><tr><td><a href="https://steemit.com/steemitboard/@steemitboard/steemitboard-witness-update-2019-01-07"><img src="https://steemitimages.com/64x128/http://i.cubeupload.com/7CiQEO.png"></a></td><td><a href="https://steemit.com/steemitboard/@steemitboard/steemitboard-witness-update-2019-01-07">SteemitBoard - Witness Update</a></td></tr></table> > Support [SteemitBoard's project](https://steemit.com/@steemitboard)! **[Vote for its witness](https://v2.steemconnect.com/sign/account-witness-vote?witness=steemitboard&approve=1)** and **get one more award**!
json metadata{"image":["https://steemitboard.com/img/notify.png"]}
Transaction InfoBlock #29279162/Trx 8671f4c7283719616ae8f13a91ef4e090c89415d
View Raw JSON Data
{
  "trx_id": "8671f4c7283719616ae8f13a91ef4e090c89415d",
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  "virtual_op": 0,
  "timestamp": "2019-01-08T15:31:33",
  "op": [
    "comment",
    {
      "parent_author": "neverless",
      "parent_permlink": "chargeback-paypal",
      "author": "steemitboard",
      "permlink": "steemitboard-notify-neverless-20190108t153132000z",
      "title": "",
      "body": "Congratulations @neverless! You received a personal award!\n\n<table><tr><td>https://steemitimages.com/70x70/http://steemitboard.com/@neverless/birthday1.png</td><td>1 Year on Steemit</td></tr></table>\n\n<sub>_[Click here to view your Board](https://steemitboard.com/@neverless)_</sub>\n\n\n**Do not miss the last post from @steemitboard:**\n<table><tr><td><a href=\"https://steemit.com/steem/@steemitboard/steemwhales-has-officially-moved-to-steemitboard-ranking\"><img src=\"https://steemitimages.com/64x128/https://cdn.steemitimages.com/DQmfRVpHQhLDhnjDtqck8GPv9NPvNKPfMsDaAFDE1D9Er2Z/header_ranking.png\"></a></td><td><a href=\"https://steemit.com/steem/@steemitboard/steemwhales-has-officially-moved-to-steemitboard-ranking\">SteemWhales has officially moved to SteemitBoard Ranking</a></td></tr><tr><td><a href=\"https://steemit.com/steemitboard/@steemitboard/steemitboard-witness-update-2019-01-07\"><img src=\"https://steemitimages.com/64x128/http://i.cubeupload.com/7CiQEO.png\"></a></td><td><a href=\"https://steemit.com/steemitboard/@steemitboard/steemitboard-witness-update-2019-01-07\">SteemitBoard - Witness Update</a></td></tr></table>\n\n> Support [SteemitBoard's project](https://steemit.com/@steemitboard)! **[Vote for its witness](https://v2.steemconnect.com/sign/account-witness-vote?witness=steemitboard&approve=1)** and **get one more award**!",
      "json_metadata": "{\"image\":[\"https://steemitboard.com/img/notify.png\"]}"
    }
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}
2018/08/31 23:25:09
voterinforma
authorneverless
permlinka-complete-amphetamine-synthese
weight0 (0.00%)
Transaction InfoBlock #25562803/Trx 83e52ec726bb4b0f78ef5b7e120d02ef253d624b
View Raw JSON Data
{
  "trx_id": "83e52ec726bb4b0f78ef5b7e120d02ef253d624b",
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  "op_in_trx": 0,
  "virtual_op": 0,
  "timestamp": "2018-08-31T23:25:09",
  "op": [
    "vote",
    {
      "voter": "informa",
      "author": "neverless",
      "permlink": "a-complete-amphetamine-synthese",
      "weight": 0
    }
  ]
}
2018/07/15 13:18:48
voterinforma
authorneverless
permlinka-complete-amphetamine-synthese
weight10000 (100.00%)
Transaction InfoBlock #24198205/Trx ca6c88f54f7081ade551b37b3c8f2aa7294153a8
View Raw JSON Data
{
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  "op": [
    "vote",
    {
      "voter": "informa",
      "author": "neverless",
      "permlink": "a-complete-amphetamine-synthese",
      "weight": 10000
    }
  ]
}
steemdelegated 5.619 SP to @neverless
2018/05/16 23:19:18
delegatorsteem
delegateeneverless
vesting shares9149.952287 VESTS
Transaction InfoBlock #22493487/Trx 45283596c426bc42f0a4bbe6093f8d1b616b7d86
View Raw JSON Data
{
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  "virtual_op": 0,
  "timestamp": "2018-05-16T23:19:18",
  "op": [
    "delegate_vesting_shares",
    {
      "delegator": "steem",
      "delegatee": "neverless",
      "vesting_shares": "9149.952287 VESTS"
    }
  ]
}
neverlessreceived 0.005 SBD, 0.003 SP author reward for @neverless / a-complete-amphetamine-synthese
2018/01/15 23:25:51
authorneverless
permlinka-complete-amphetamine-synthese
sbd payout0.005 SBD
steem payout0.000 STEEM
vesting payout4.095361 VESTS
Transaction InfoBlock #19012346/Virtual Operation #12
View Raw JSON Data
{
  "trx_id": "0000000000000000000000000000000000000000",
  "block": 19012346,
  "trx_in_block": 4294967295,
  "op_in_trx": 0,
  "virtual_op": 12,
  "timestamp": "2018-01-15T23:25:51",
  "op": [
    "author_reward",
    {
      "author": "neverless",
      "permlink": "a-complete-amphetamine-synthese",
      "sbd_payout": "0.005 SBD",
      "steem_payout": "0.000 STEEM",
      "vesting_payout": "4.095361 VESTS"
    }
  ]
}
neverlessupdated their account properties
2018/01/09 14:32:45
accountneverless
owner{"weight_threshold":1,"account_auths":[],"key_auths":[["STM6yEWYZVMk3LzBtWQurV5xPhxsjrYgoYUF6ZMz1EyD8wp92NxwJ",1]]}
active{"weight_threshold":1,"account_auths":[],"key_auths":[["STM6ruFmuqHE6MWErpkVr9USS7BeJB7mQnaJC4DBaJu4rBhzXUSxS",1]]}
posting{"weight_threshold":1,"account_auths":[["dtube.app",1]],"key_auths":[["STM6vr4meB9H2SgW1CA4zsdGY243uxXr2jbWAus3x7aqYYtAz9JWe",1]]}
memo keySTM7isqcJrnEyaS8rjN7uPtptr1NCrhC3K1yC3XCehYqxkHY5crvb
json metadata{"profile":{"profile_image":"http://fs1.directupload.net/images/180108/quwvj2te.jpg","cover_image":"http://fs1.directupload.net/images/180108/vzsrxknz.jpg","name":"NEVERLESS","about":"UNLEASHED CRIME","location":"127.0.0.1"}}
Transaction InfoBlock #18829046/Trx b5377a788fb1be01b738a3a63932b2bf49be4c0f
View Raw JSON Data
{
  "trx_id": "b5377a788fb1be01b738a3a63932b2bf49be4c0f",
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  "timestamp": "2018-01-09T14:32:45",
  "op": [
    "account_update",
    {
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      "owner": {
        "weight_threshold": 1,
        "account_auths": [],
        "key_auths": [
          [
            "STM6yEWYZVMk3LzBtWQurV5xPhxsjrYgoYUF6ZMz1EyD8wp92NxwJ",
            1
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        ]
      },
      "active": {
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        "account_auths": [],
        "key_auths": [
          [
            "STM6ruFmuqHE6MWErpkVr9USS7BeJB7mQnaJC4DBaJu4rBhzXUSxS",
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      },
      "posting": {
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        "account_auths": [
          [
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        ],
        "key_auths": [
          [
            "STM6vr4meB9H2SgW1CA4zsdGY243uxXr2jbWAus3x7aqYYtAz9JWe",
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      },
      "memo_key": "STM7isqcJrnEyaS8rjN7uPtptr1NCrhC3K1yC3XCehYqxkHY5crvb",
      "json_metadata": "{\"profile\":{\"profile_image\":\"http://fs1.directupload.net/images/180108/quwvj2te.jpg\",\"cover_image\":\"http://fs1.directupload.net/images/180108/vzsrxknz.jpg\",\"name\":\"NEVERLESS\",\"about\":\"UNLEASHED CRIME\",\"location\":\"127.0.0.1\"}}"
    }
  ]
}
2018/01/09 13:34:57
required auths[]
required posting auths["neverless"]
idfollow
json["follow",{"follower":"neverless","following":"dtube","what":["blog"]}]
Transaction InfoBlock #18827890/Trx 23fff33a19b29aee641e3a0b2242a48849e9d400
View Raw JSON Data
{
  "trx_id": "23fff33a19b29aee641e3a0b2242a48849e9d400",
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  "trx_in_block": 5,
  "op_in_trx": 0,
  "virtual_op": 0,
  "timestamp": "2018-01-09T13:34:57",
  "op": [
    "custom_json",
    {
      "required_auths": [],
      "required_posting_auths": [
        "neverless"
      ],
      "id": "follow",
      "json": "[\"follow\",{\"follower\":\"neverless\",\"following\":\"dtube\",\"what\":[\"blog\"]}]"
    }
  ]
}
2018/01/09 12:45:09
voterneverless
authorneverless
permlinkchargeback-paypal
weight10000 (100.00%)
Transaction InfoBlock #18826894/Trx 94aaff275e1eaa75ac94088d5d696520643c9fe0
View Raw JSON Data
{
  "trx_id": "94aaff275e1eaa75ac94088d5d696520643c9fe0",
  "block": 18826894,
  "trx_in_block": 11,
  "op_in_trx": 0,
  "virtual_op": 0,
  "timestamp": "2018-01-09T12:45:09",
  "op": [
    "vote",
    {
      "voter": "neverless",
      "author": "neverless",
      "permlink": "chargeback-paypal",
      "weight": 10000
    }
  ]
}
2018/01/09 12:45:00
voterneverless
authorneverless
permlinktut-kostenloses-vape-liquid-bekommen
weight10000 (100.00%)
Transaction InfoBlock #18826891/Trx d5bd6fd867d4d80b8ffd458935a1cd6d2df89fd9
View Raw JSON Data
{
  "trx_id": "d5bd6fd867d4d80b8ffd458935a1cd6d2df89fd9",
  "block": 18826891,
  "trx_in_block": 50,
  "op_in_trx": 0,
  "virtual_op": 0,
  "timestamp": "2018-01-09T12:45:00",
  "op": [
    "vote",
    {
      "voter": "neverless",
      "author": "neverless",
      "permlink": "tut-kostenloses-vape-liquid-bekommen",
      "weight": 10000
    }
  ]
}
neverlessunfollowed @dtube
2018/01/09 12:44:27
required auths[]
required posting auths["neverless"]
idfollow
json["follow",{"follower":"neverless","following":"dtube","what":[]}]
Transaction InfoBlock #18826880/Trx 64b00a945045dae14f9dd4a60ef894b1f49c8865
View Raw JSON Data
{
  "trx_id": "64b00a945045dae14f9dd4a60ef894b1f49c8865",
  "block": 18826880,
  "trx_in_block": 5,
  "op_in_trx": 0,
  "virtual_op": 0,
  "timestamp": "2018-01-09T12:44:27",
  "op": [
    "custom_json",
    {
      "required_auths": [],
      "required_posting_auths": [
        "neverless"
      ],
      "id": "follow",
      "json": "[\"follow\",{\"follower\":\"neverless\",\"following\":\"dtube\",\"what\":[]}]"
    }
  ]
}
2018/01/09 03:45:30
parent authorneverless
parent permlinka-complete-amphetamine-synthese
authorcheetah
permlinkcheetah-re-neverlessa-complete-amphetamine-synthese
title
bodyHi! I am a robot. I just upvoted you! I found similar content that readers might be interested in: https://www.scribd.com/doc/59694589/Amphetamine-Synthese
json metadata
Transaction InfoBlock #18816115/Trx 6fc2ceeec0e6f5099b36b6c4e3d1e96efe801e5d
View Raw JSON Data
{
  "trx_id": "6fc2ceeec0e6f5099b36b6c4e3d1e96efe801e5d",
  "block": 18816115,
  "trx_in_block": 17,
  "op_in_trx": 0,
  "virtual_op": 0,
  "timestamp": "2018-01-09T03:45:30",
  "op": [
    "comment",
    {
      "parent_author": "neverless",
      "parent_permlink": "a-complete-amphetamine-synthese",
      "author": "cheetah",
      "permlink": "cheetah-re-neverlessa-complete-amphetamine-synthese",
      "title": "",
      "body": "Hi! I am a robot. I just upvoted you! I found similar content that readers might be interested in:\nhttps://www.scribd.com/doc/59694589/Amphetamine-Synthese",
      "json_metadata": ""
    }
  ]
}
2018/01/09 03:45:27
votercheetah
authorneverless
permlinka-complete-amphetamine-synthese
weight8 (0.08%)
Transaction InfoBlock #18816114/Trx b89a759d95791c08130156d6315a73cf117501dd
View Raw JSON Data
{
  "trx_id": "b89a759d95791c08130156d6315a73cf117501dd",
  "block": 18816114,
  "trx_in_block": 2,
  "op_in_trx": 0,
  "virtual_op": 0,
  "timestamp": "2018-01-09T03:45:27",
  "op": [
    "vote",
    {
      "voter": "cheetah",
      "author": "neverless",
      "permlink": "a-complete-amphetamine-synthese",
      "weight": 8
    }
  ]
}
2018/01/09 00:55:00
voterzurax
authorneverless
permlinktut-kostenloses-vape-liquid-bekommen
weight10000 (100.00%)
Transaction InfoBlock #18812711/Trx 34b7b0ab99ab698bc808687c873a0513fdd42d56
View Raw JSON Data
{
  "trx_id": "34b7b0ab99ab698bc808687c873a0513fdd42d56",
  "block": 18812711,
  "trx_in_block": 37,
  "op_in_trx": 0,
  "virtual_op": 0,
  "timestamp": "2018-01-09T00:55:00",
  "op": [
    "vote",
    {
      "voter": "zurax",
      "author": "neverless",
      "permlink": "tut-kostenloses-vape-liquid-bekommen",
      "weight": 10000
    }
  ]
}
neverlesspublished a new post: chargeback-paypal
2018/01/08 23:59:33
parent author
parent permlinkpaypal
authorneverless
permlinkchargeback-paypal
titleChargeback Paypal
body@@ -4,32 +4,8 @@ ml%3E%0A -%3Cp%3E%3Cbr%3E%3C/p%3E%0A%3Cp%3E%3Cbr%3E%3C/p%3E%0A %3Cp%3E%3C
json metadata{"tags":["paypal","chargeback","methode"],"app":"steemit/0.1","format":"html"}
Transaction InfoBlock #18811603/Trx a2f45232c64de144a6dbcc75c7944d00d05392a5
View Raw JSON Data
{
  "trx_id": "a2f45232c64de144a6dbcc75c7944d00d05392a5",
  "block": 18811603,
  "trx_in_block": 17,
  "op_in_trx": 0,
  "virtual_op": 0,
  "timestamp": "2018-01-08T23:59:33",
  "op": [
    "comment",
    {
      "parent_author": "",
      "parent_permlink": "paypal",
      "author": "neverless",
      "permlink": "chargeback-paypal",
      "title": "Chargeback Paypal",
      "body": "@@ -4,32 +4,8 @@\n ml%3E%0A\n-%3Cp%3E%3Cbr%3E%3C/p%3E%0A%3Cp%3E%3Cbr%3E%3C/p%3E%0A\n %3Cp%3E%3C\n",
      "json_metadata": "{\"tags\":[\"paypal\",\"chargeback\",\"methode\"],\"app\":\"steemit/0.1\",\"format\":\"html\"}"
    }
  ]
}
neverlesspublished a new post: chargeback-paypal
2018/01/08 23:59:15
parent author
parent permlinkpaypal
authorneverless
permlinkchargeback-paypal
titleChargeback Paypal
body@@ -537,17 +537,16 @@ en.%3Cbr%3E%0A - Change y
json metadata{"tags":["paypal","chargeback","methode"],"app":"steemit/0.1","format":"html"}
Transaction InfoBlock #18811597/Trx 4e108a552bb34bed59907c437b0cdcc8e10b64be
View Raw JSON Data
{
  "trx_id": "4e108a552bb34bed59907c437b0cdcc8e10b64be",
  "block": 18811597,
  "trx_in_block": 32,
  "op_in_trx": 0,
  "virtual_op": 0,
  "timestamp": "2018-01-08T23:59:15",
  "op": [
    "comment",
    {
      "parent_author": "",
      "parent_permlink": "paypal",
      "author": "neverless",
      "permlink": "chargeback-paypal",
      "title": "Chargeback Paypal",
      "body": "@@ -537,17 +537,16 @@\n en.%3Cbr%3E%0A\n- \n Change y\n",
      "json_metadata": "{\"tags\":[\"paypal\",\"chargeback\",\"methode\"],\"app\":\"steemit/0.1\",\"format\":\"html\"}"
    }
  ]
}
neverlesspublished a new post: chargeback-paypal
2018/01/08 23:58:18
parent author
parent permlinkpaypal
authorneverless
permlinkchargeback-paypal
titleChargeback Paypal
body<html> <p><br></p> <p><br></p> <p><strong>Since I am out of paypal chargeback service months now and I dont mind to start again I will share my methods.</strong>&nbsp;</p> <p>&nbsp;</p> <p><strong>Normal Payments</strong><br> &nbsp;</p> <p>For normal payments you always can call paypal and lie them about item &nbsp;that didnt recived or open a dispute using resolution center.<br> &nbsp;</p> <p><strong>Family And Friends</strong><br> &nbsp;</p> <p>For family and friends i used to change ip and location so the account look like stolen.<br> Change your security answers and password and you will be able to open a &nbsp;refund as unauthorized transaction,say that you were hacked or &nbsp;something like that.<br> &nbsp;</p> <p>Chargedback over 10.000$ while did it.<br> &nbsp;</p> <p>Good luck &nbsp;&nbsp;;)</p> </html>
json metadata{"tags":["paypal","chargeback","methode"],"app":"steemit/0.1","format":"html"}
Transaction InfoBlock #18811578/Trx b584e546695a8fea5adc044df6882e54c8922530
View Raw JSON Data
{
  "trx_id": "b584e546695a8fea5adc044df6882e54c8922530",
  "block": 18811578,
  "trx_in_block": 15,
  "op_in_trx": 0,
  "virtual_op": 0,
  "timestamp": "2018-01-08T23:58:18",
  "op": [
    "comment",
    {
      "parent_author": "",
      "parent_permlink": "paypal",
      "author": "neverless",
      "permlink": "chargeback-paypal",
      "title": "Chargeback Paypal",
      "body": "<html>\n<p><br></p>\n<p><br></p>\n<p><strong>Since I am out of paypal chargeback service months now and I dont mind to start again I will share my methods.</strong>&nbsp;</p>\n<p>&nbsp;</p>\n<p><strong>Normal Payments</strong><br>\n&nbsp;</p>\n<p>For normal payments you always can call paypal and lie them about item &nbsp;that didnt recived or open a dispute using resolution center.<br>\n&nbsp;</p>\n<p><strong>Family And Friends</strong><br>\n&nbsp;</p>\n<p>For family and friends i used to change ip and location so the account look like stolen.<br>\n Change your security answers and password and you will be able to open a &nbsp;refund as unauthorized transaction,say that you were hacked or &nbsp;something like that.<br>\n&nbsp;</p>\n<p>Chargedback over 10.000$ while did it.<br>\n&nbsp;</p>\n<p>Good luck &nbsp;&nbsp;;)</p>\n</html>",
      "json_metadata": "{\"tags\":[\"paypal\",\"chargeback\",\"methode\"],\"app\":\"steemit/0.1\",\"format\":\"html\"}"
    }
  ]
}
2018/01/08 23:50:48
parent author
parent permlinkdeutsch
authorneverless
permlinktut-kostenloses-vape-liquid-bekommen
title[TUT] Kostenloses Vape Liquid bekommen!
body@@ -423,15 +423,9 @@ eld -&nbsp;Z +z ur%C3%BCc @@ -434,16 +434,17 @@ rstatten +, oder ei @@ -455,9 +455,18 @@ ues -Z +Fl%C3%A4schen z usen
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Transaction InfoBlock #18811429/Trx 40cd3241e0a11ce1d31be8aa950db52d26b997c1
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2018/01/08 23:49:42
parent author
parent permlinkdeutsch
authorneverless
permlinktut-kostenloses-vape-liquid-bekommen
title[TUT] Kostenloses Vape Liquid bekommen!
body<html> <h2><strong>1. Ihr geht auf die Website eines X beliebigen Versandhändlers der Liquids führt</strong></h2> <h2><strong>2. Ihr bestellt euch ganz normal ein Liquid an eure Adresse.</strong>&nbsp;</h2> <h2><strong>3. Wenn es angekommen ist, schreibt ihr dem Verkäufer eine Email und teilt ihm darin mit, dass bei dem Versand das Fläschchen aufgegangen ist.</strong></h2> <p><br></p> <p><em>Er wird euch entweder das Geld &nbsp;Zurückerstatten oder ein neues Zusenden.&nbsp;</em></p> </html>
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Transaction InfoBlock #18811407/Trx d31f37375bfc2c5fe91372094d48c3de17cf1096
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neverlessupdated their account properties
2018/01/08 23:42:21
accountneverless
memo keySTM6SP5SfbFfyhYHYL6SYsgZgGF2mFtCL7wXRX92LRJHKrPX75787
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Transaction InfoBlock #18811260/Trx 88adc7e0e97cdea60cf66200ad068ba389db5985
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2018/01/08 23:31:30
parent author
parent permlinkchemiacal
authorneverless
permlinka-complete-amphetamine-synthese
titleA Complete Amphetamine Synthese.
body![bild1.jpg](https://steemitimages.com/DQmZtYLErVcD3gJrDSDK7Bke14ycbANiFySUAXQtYB3NdNQ/bild1.jpg) This is everything you need for making P2NP, from left to right: Pipette-aparatus, several pipettes, dean&stark trap, PTFE greas, toluene, measuring cylinder 100ml, nitroethane, benzaldehyde, n-butylamine, above the brown flask a heating mantle and a 250ml RB-flask. The ratio s you should use are 1mol benzaldehyde and 1 mol nitroethane and 0,1mol R-NH2. Converting mols to ml s you will find out that you will need: SWIM didn t use 1 mol right away but first wanted to experiment with smaller amounts, so he used: 17ml benzaldehyde 13,3ml nitroethane 3,3ml n-butylamine 33ml toluene ============================================================================== Be sure that non of the products you use will contain water since when performing the reaction water will evolve which will be taken out of the reaction with the dean&stark trap because it prevents a good yield of P2NP. ![bild2.jpg](https://steemitimages.com/DQmURrkAdLg3Xj3Npq6c41K9LPfVRqn1WoF3VfU6CYcs7SS/bild2.jpg) All the chemicals mixed together. ![bild3.jpg](https://steemitimages.com/DQmd3RBEJZ4P6F5AX2R6NPKKdijjKiWQjxh9DTTm3XRBdwj/bild3.jpg) An overall view ============================================================================== ![bild4.jpg](https://steemitimages.com/DQmWw4pd8Sc9YZtLRNgMDaUvRUB6s2dYQmx8X9VjRB7CSW4/bild4.jpg) After heating it a bit to get it at 100*C aprox. ![bild5.jpg](https://steemitimages.com/DQmUNS6QovqforkZNgDytsjSMw8kDS5KzDerSpkYRzRdeS1/bild5.jpg) A vague picture of how it looks like after 3 hours of refluxing, if the color will get orange to dark orange before 6 hours you should stop refluxing at that time. But don t reflux it longer than 6 hours, sometimes you only need 3 hours though. To improve yield you can also add 1ml of glacial acetic acid to buffer the n-butylamine. For every mole of benzaldehyde one mole of water will form and since SWIM used 17ml of benzaldehyde which is ( 17ml x 1,05g/ml = 17,85g benzaldehyde / 106,12g/mol = ) 0,17mol benzaldehyde. Thus 0,17 mol of water will form which is ( 0,17 x 18,01 = ) 3,03ml of water. So after the 6 hours or earlier you should have 3,03ml of water in your trap, it will likely be more since your toluene will contain a bit of water too in SWIMS reaction he got 4ml of water. ============================================================================== ![bild6.jpg](https://steemitimages.com/DQmXB2RFKbBjT8XRDXoBvCxEq63iKTeEnFEyWbcU3ij9HfT/bild6.jpg) The color after 6 hours of refluxing and collecting 4ml of water in the trap. Now SWIM puts the round bottom flask in the freezer at 18*C because the P2NP is now dissolved in the toluene but when you will make the toluene very cold the P2NP won t dissolve in the toluene anymore or at least very bad. 7 hours later scratched the walls of the RB flask to initiate crystal forming. 10 hours later a lot of crystals in the RB flask, ![bild7.jpg](https://steemitimages.com/DQmeioX6nn5B7rnvzCP5TspnHrX6wz2UH2oPah2D414zpuk/bild7.jpg) The crop of crystals in the bottom of the flask. ============================================================================== ![bild8.jpg](https://steemitimages.com/DQmTgXbDXq9pTDp9H67hpFvTSTXRnmoarrZdqs3bjdEpZa6/bild8.jpg) Crystals formed on the sides. ![bild9.jpg](https://steemitimages.com/DQmWUGqfYmAi5CJYBqy9Y3hok7ZdcKDhXPfBgCdTVm8k1Hw/bild9.jpg) Now quickly break up the mass with a glass stir rod or a thermometer and throw the mixture threw a buchner filter (filtration under vacuum). The toluene will get back to room temperature and thus the crystals will dissolve back into the toluene that is why you need to be so quick and necesarilly do need to use a buchner filter. ============================================================================== ![bild10.jpg](https://steemitimages.com/DQmfKARNU4GUnye8LNpLTPZwXeguyrQHMbsE1HpnuUc52P3/bild10.jpg) Just a picture of the buchner filter how it looks like. Put the crystals on a paper to air-dry. As you can see the crystals are yellow coloured so they need purification or else your next product will be crap and yellow too. The first crop weighed 6,02 gram when completely dry. The second crop was 8,01gram SWIM evaporated off the half of the liquid and put it back in the fridge. ![bild11.jpg](https://steemitimages.com/DQmPzQiET1CTEZbq3f3C1weWTvKfjyA6kcjwUQihDxfG2Rv/bild11.jpg) Evaporating off the half of the toluene. ![bild12.jpg](https://steemitimages.com/DQmemD8GF5W6Dh4gsS4fKAoLJ4Qq9wUGHMNzCR45BAbpizV/bild12.jpg) Toluene and water seperated. ============================================================================== Now the crystals were purified by dissolving them in a minimal amount of boiling isopropylalcohol which is standing in a hot water bath, when they have all dissolved put a watch glass over the top of the erlenmyer and let them cool to room temperature; then put them in the deep freezer and vacuum filtrate them over a buchner filter and let them dry again. ![bild13.jpg](https://steemitimages.com/DQmZJAVYxyiso3a7x49i4XZtje3Qi12N3RiECFMSX78iP14/bild13.jpg) ![bild14.jpg](https://steemitimages.com/DQmcRhh9is4yenxSdZFnQVpoSQErDaQVa8vv2CPCFe1BZJf/bild14.jpg) Beaker with IPA standing in beaker with water. On the right the P2NP crystals. ![bild15.jpg](https://steemitimages.com/DQmTtDvyaZXL5uCavPfRwS5jqqSi7Uc8XXwg68rcWS5QCLD/bild15.jpg) ![bild16.jpg](https://steemitimages.com/DQma86bD6J1r3h7dVPMCnXL3B1xYtgfhNWxXynz8SKyQNcH/bild16.jpg) P2NP dissolved in boiling IPA. Cooling down, you can see crystals forming ![h1.jpg](https://steemitimages.com/DQmcDWBrPtYExYpZhJQzhvESfmXrjXz9JtEyaNb54UMbvzU/h1.jpg) ![h2.jpg](https://steemitimages.com/DQmXhJu28irCN27Cz6PsfKo6b7rFsYkQQkyRHUoaHskxpiP/h2.jpg) ![h3.jpg](https://steemitimages.com/DQmNWz3wHuQcDzw2yTHhFeLk3FpbzWqbbswtCg7MeyEJTka/h3.jpg) ![h4.jpg](https://steemitimages.com/DQmNQyiiLAZkDkjRdy2jk9oEGaCtWn5SY77A4gvwN8krEaW/h4.jpg) Here you can see the crystals forming while cooling down, in the buchner filter the crystals were washed with water. From the 14,03g of P2NP which SWIM started with 13,7g of P2NP was left over after the recrystalization/purification step. ============================================================================== Now it is time (by the mean time the P2NP is dry again ;-) ) to do the aminated reduction of the P2NP to amphetamine.freebase. This was first tested with 3,5g of P2NP: You will need 5g Al foil cut it into 1 (2,5cm) squares and then fold them up to nuggets and you should wrap them up so tight that you can only still press them a little with your fingers. ![g1.jpg](https://steemitimages.com/DQmPMTpQej9yE623D1qRfroNvzeccKSZt8NukN62vRP8VpK/g1.jpg) This is the reflux setup that SWIM will be using. ![g2.jpg](https://steemitimages.com/DQmPEHgHce3wE1FdeUtzt8T8S7x9eoMmqDmAQM37xFTWaSs/g2.jpg) Close up and methanol added which had 70mg of HgCl2 dissolved in it As sayd above at the picture you will need a solvent like methanol and you dissolve HgCl2 inside the solvent and add it to the Aluminium make sure the aluminium is not too fine else a very heavy reaction will occur with the possibilty that mercury and hydrochloric acid, boiling methanol and hot aluminium will cover you like a vulcano. The HgCl2 can also be substituted by other Hg salts like Hg(NO3)2. ============================================================================== After 10min average the Al will start to evolve hydrogen gas, depending on thickness of the foil. If you use thin foil wrap it up 3-4 layers before cuting squares out of it else it will react too heavily. ![g3.jpg](https://steemitimages.com/DQmNy4TZMhHs8CPqQAHK8j4eH12tgAzRVcwRx8qhfjZ6u2g/g3.jpg) The methanol will become gray/blue, and the aluminium will become less shiny. On for hand you should make a solution of your P2NP that will be added to the mixture later on. The solvent used was isopropylalcohol and glacial acetic acid, in a ratio: 40ml IPA; 60ml GAA; 3,5g P2NP You might need to heat it up because the P2NP will not dissolve easily at room temperature. ============================================================================== ![g4.jpg](https://steemitimages.com/DQmbLq3Bty1V6SQs4bzVPSZ67iJ42TX7v7AosPnvhoDGag1/g4.jpg) The reaction will heat up and when there are dark spots on the Al and there is hydrogen gas bubbling of it you can add all the P2NP solution at once to the Al+MeOH+HgCl2. ![g5.jpg](https://steemitimages.com/DQmVFXu6yscbvUpnJrFRF2hNfb8A8998fwtErZB4L8WEDVH/g5.jpg) A little later in the progress, the mixture gets darker and heats up even more to a mild reflux ============================================================================== ![g6.jpg](https://steemitimages.com/DQmST8fPyfDCUWdGBQp8DTuQox1j9wXzVMEanmckUeqxBkv/g6.jpg) By now the mixture is dark and the aluminium is dissolving slowely, you can notice small shiny pieces of aluminium floating around, extra heat is applied here because the Al was so big that it reacted not fast enough, but hey better slow reaction than a volcano, right. ![g7.jpg](https://steemitimages.com/DQmQDdzBZFureDPSd12EWsghqDJ1M5bkG58BaUGGw7hx1bS/g7.jpg) Now when almost all the Al has dissolved add 200ml of cold water to the mixture to cool it down. Then basify it to pH 12 with 50g of NaOH dissolved in 150ml water. All the remaining Al will now react with the NaOH and form hydrogen gas and the mixture will heat up but not to a boil, that wouldn t matter though. ============================================================================== ![a1.jpg](https://steemitimages.com/DQmWbYm97hyWrNhfPcTBoiwtn6kSf4jSQNPArHguycQZpRn/a1.jpg) ![a2.jpg](https://steemitimages.com/DQmPcYpn4CxJKEJopREhCfBMd7GjZynTqqDof9DEM7UFNxZ/a2.jpg) After all the washed this was collected in total. Anhydrous magnesiumsulfate was added to suck up the water in their molecules and thus drying the ether and your product. Now you only have to wait 12 hours to let the MgSO4 do it s work, filtrate it and then you can let the ether evaporate off at room temperature or with the help of a warm lamp. NOT AN OPEN FLAME!!! Ether is very inflammable. All the ether was evaporated off and 50ml anhydrous IPA was added to the amphetamine.freebase. Then to anhydrous IPA 98% sulfuric acid was added calculate how many mol amphetamine freebase you ve got and then take 90% of that and calculate how many mols of H2SO4 that represents and add that to 15ml of anhydrous IPA. Now drip H2SO4+IPA mix into the freebase which is dissolved in the IPA. Here you can see the crystals forming after a few drops have been added. ![a3.jpg](https://steemitimages.com/DQmZjSv8N85rewNkgPyBz7d5SY8bEJyZ22QMTfFab7k3C43/a3.jpg) ============================================================================== ![a4.jpg](https://steemitimages.com/DQmPqzjBQdNVy35DobzRoj3C6KotUE4Q6aUwUAVqq9PSCny/a4.jpg) Glass full of crystals. It wasn t that much though but it looks like it is full of crystals. ![a5.jpg](https://steemitimages.com/DQmbVUDoXPGgBqMLc3dCAoz1cV49xdX4WegzN4G19cWy7qj/a5.jpg) Filtrate it. ![a6.jpg](https://steemitimages.com/DQmdonBD7WVoyujnVuaarTms8xSKfkWTMLbGgLBn7UBArXG/a6.jpg) And finally pure amphetamine sulfate has been obtained this was around 180mg. When only starting with 3,5g P2NP, when you loose 1g in the filter that is a lot, with bigger amounts yields are better anyway. ============================================================================== This was a complete amphetamine synthese. ~neverless
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Transaction InfoBlock #18811044/Trx bc1af8558296b97f7997c53aec861aa98aae47f5
View Raw JSON Data
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      "author": "neverless",
      "permlink": "a-complete-amphetamine-synthese",
      "title": "A Complete Amphetamine Synthese.",
      "body": "![bild1.jpg](https://steemitimages.com/DQmZtYLErVcD3gJrDSDK7Bke14ycbANiFySUAXQtYB3NdNQ/bild1.jpg)\n\n\nThis is everything you need for making P2NP, from left to right: Pipette-aparatus, several pipettes, dean&stark trap, PTFE greas, toluene, measuring cylinder 100ml, nitroethane, benzaldehyde, n-butylamine, above the brown flask a heating mantle and a 250ml RB-flask.  \n\nThe ratio s you should use are 1mol benzaldehyde and 1 mol nitroethane and 0,1mol R-NH2. Converting mols to ml s you will find out that you will need: SWIM didn t use 1 mol right away but first wanted to experiment with smaller amounts, so he used: \n\n17ml benzaldehyde  13,3ml nitroethane  3,3ml n-butylamine 33ml toluene  \n\n==============================================================================\n\nBe sure that non of the products you use will contain water since when performing the reaction water will evolve which will be taken out of the reaction with the dean&stark trap because it prevents a good yield of P2NP.  \n\n![bild2.jpg](https://steemitimages.com/DQmURrkAdLg3Xj3Npq6c41K9LPfVRqn1WoF3VfU6CYcs7SS/bild2.jpg)\nAll the chemicals mixed together.\n\n![bild3.jpg](https://steemitimages.com/DQmd3RBEJZ4P6F5AX2R6NPKKdijjKiWQjxh9DTTm3XRBdwj/bild3.jpg)\nAn overall view \n\n==============================================================================\n\n![bild4.jpg](https://steemitimages.com/DQmWw4pd8Sc9YZtLRNgMDaUvRUB6s2dYQmx8X9VjRB7CSW4/bild4.jpg)\nAfter heating it a bit to get it at 100*C aprox.  \n\n![bild5.jpg](https://steemitimages.com/DQmUNS6QovqforkZNgDytsjSMw8kDS5KzDerSpkYRzRdeS1/bild5.jpg)\n\nA vague picture of how it looks like after 3 hours of refluxing, if the color will get orange to dark orange before 6 hours you should stop refluxing at that time. But don t reflux it longer than 6 hours, sometimes you only need 3 hours though. To improve yield you can also add 1ml of glacial acetic acid to buffer the n-butylamine. For every mole of benzaldehyde one mole of water will form and since SWIM used 17ml of benzaldehyde which is ( 17ml x 1,05g/ml = 17,85g benzaldehyde / 106,12g/mol = ) 0,17mol benzaldehyde. Thus 0,17 mol of water will form which is ( 0,17 x 18,01 = ) 3,03ml of water. So after the 6 hours or earlier you should have 3,03ml of water in your trap, it will likely be more since your toluene will contain a bit of water too in SWIMS reaction he got 4ml of water.     \n\n==============================================================================\n\n![bild6.jpg](https://steemitimages.com/DQmXB2RFKbBjT8XRDXoBvCxEq63iKTeEnFEyWbcU3ij9HfT/bild6.jpg)\n\nThe color after 6 hours of refluxing and collecting 4ml of water in the trap. Now SWIM puts the round bottom flask in the freezer at 18*C because the P2NP is now dissolved in the toluene but when you will make the toluene very cold the P2NP won t dissolve in the toluene anymore or at least very bad.  \n7 hours later scratched the walls of the RB flask to initiate crystal forming. 10 hours later a lot of crystals in the RB flask, \n\n![bild7.jpg](https://steemitimages.com/DQmeioX6nn5B7rnvzCP5TspnHrX6wz2UH2oPah2D414zpuk/bild7.jpg)\nThe crop of crystals in the bottom of the flask. \n\n==============================================================================\n\n![bild8.jpg](https://steemitimages.com/DQmTgXbDXq9pTDp9H67hpFvTSTXRnmoarrZdqs3bjdEpZa6/bild8.jpg)\nCrystals formed on the sides. \n\n![bild9.jpg](https://steemitimages.com/DQmWUGqfYmAi5CJYBqy9Y3hok7ZdcKDhXPfBgCdTVm8k1Hw/bild9.jpg)\n\nNow quickly break up the mass with a glass stir rod or a thermometer and throw the mixture threw a buchner filter (filtration under vacuum). The toluene will get back to room temperature and thus the crystals will dissolve back into the toluene that is why you need to be so quick and necesarilly do need to use a buchner filter. \n\n==============================================================================\n\n\n![bild10.jpg](https://steemitimages.com/DQmfKARNU4GUnye8LNpLTPZwXeguyrQHMbsE1HpnuUc52P3/bild10.jpg)\nJust a picture of the buchner filter how it looks like. Put the crystals on a paper to air-dry.  \nAs you can see the crystals are yellow coloured so they need purification or else your next product will be crap and yellow too. The first crop weighed 6,02 gram when completely dry. The second crop was 8,01gram SWIM evaporated off the half of the liquid and put it back in the fridge.\n\n![bild11.jpg](https://steemitimages.com/DQmPzQiET1CTEZbq3f3C1weWTvKfjyA6kcjwUQihDxfG2Rv/bild11.jpg)\nEvaporating off the half of the toluene. \n![bild12.jpg](https://steemitimages.com/DQmemD8GF5W6Dh4gsS4fKAoLJ4Qq9wUGHMNzCR45BAbpizV/bild12.jpg)\n Toluene and water seperated.\n\n==============================================================================\n\n Now the crystals were purified by dissolving them in a minimal amount of boiling isopropylalcohol which is standing in a hot water bath, when they have all dissolved put a watch glass over the top of the erlenmyer and let them cool to room temperature; then put them in the deep freezer and vacuum filtrate them over a buchner filter and let them dry again.\n![bild13.jpg](https://steemitimages.com/DQmZJAVYxyiso3a7x49i4XZtje3Qi12N3RiECFMSX78iP14/bild13.jpg)\n![bild14.jpg](https://steemitimages.com/DQmcRhh9is4yenxSdZFnQVpoSQErDaQVa8vv2CPCFe1BZJf/bild14.jpg)\nBeaker with IPA standing in beaker with water. On the right the P2NP crystals.\n\n![bild15.jpg](https://steemitimages.com/DQmTtDvyaZXL5uCavPfRwS5jqqSi7Uc8XXwg68rcWS5QCLD/bild15.jpg)\n![bild16.jpg](https://steemitimages.com/DQma86bD6J1r3h7dVPMCnXL3B1xYtgfhNWxXynz8SKyQNcH/bild16.jpg)\nP2NP dissolved in boiling IPA.            Cooling down, you can see crystals forming\n\n\n![h1.jpg](https://steemitimages.com/DQmcDWBrPtYExYpZhJQzhvESfmXrjXz9JtEyaNb54UMbvzU/h1.jpg)\n![h2.jpg](https://steemitimages.com/DQmXhJu28irCN27Cz6PsfKo6b7rFsYkQQkyRHUoaHskxpiP/h2.jpg)\n![h3.jpg](https://steemitimages.com/DQmNWz3wHuQcDzw2yTHhFeLk3FpbzWqbbswtCg7MeyEJTka/h3.jpg)\n![h4.jpg](https://steemitimages.com/DQmNQyiiLAZkDkjRdy2jk9oEGaCtWn5SY77A4gvwN8krEaW/h4.jpg)\nHere you can see the crystals forming while cooling down, in the buchner filter the crystals were washed with water.  \nFrom the 14,03g of P2NP which SWIM started with 13,7g of P2NP was left over after the recrystalization/purification step. \n\n==============================================================================\n\n Now it is time (by the mean time the P2NP is dry again ;-) ) to do the aminated reduction of the P2NP to amphetamine.freebase.  \nThis was first tested with 3,5g of P2NP:  \nYou will need 5g Al foil cut it into 1 (2,5cm) squares and then fold them up to nuggets and you should wrap them up so tight that you can only still press them a little with your fingers.\n\n![g1.jpg](https://steemitimages.com/DQmPMTpQej9yE623D1qRfroNvzeccKSZt8NukN62vRP8VpK/g1.jpg)\nThis is the reflux setup that SWIM will be using. \n![g2.jpg](https://steemitimages.com/DQmPEHgHce3wE1FdeUtzt8T8S7x9eoMmqDmAQM37xFTWaSs/g2.jpg)\n Close up and methanol added which had 70mg of HgCl2 dissolved in it\n\nAs sayd above at the picture you will need a solvent like methanol and you dissolve HgCl2 inside the solvent and add it to the Aluminium make sure the aluminium is not too fine else a very heavy reaction will occur with the possibilty that mercury and hydrochloric acid, boiling methanol and hot aluminium will cover you like a vulcano. The HgCl2 can also be substituted by other Hg salts like Hg(NO3)2. \n\n==============================================================================\n\nAfter 10min average the Al will start to evolve hydrogen gas, depending on thickness of the foil. If you use thin foil wrap it up 3-4 layers before cuting squares out of it else it will react too heavily. \n\n![g3.jpg](https://steemitimages.com/DQmNy4TZMhHs8CPqQAHK8j4eH12tgAzRVcwRx8qhfjZ6u2g/g3.jpg)\nThe methanol will become gray/blue, and the aluminium will become less shiny. \n\nOn for hand you should make a solution of your P2NP that will be added to the mixture later on. The solvent used was isopropylalcohol and glacial acetic acid, in a ratio:\n\n 40ml IPA; 60ml GAA; 3,5g P2NP\n\nYou might need to heat it up because the P2NP will not dissolve easily at room temperature.\n\n==============================================================================\n\n![g4.jpg](https://steemitimages.com/DQmbLq3Bty1V6SQs4bzVPSZ67iJ42TX7v7AosPnvhoDGag1/g4.jpg)\nThe reaction will heat up and when there are dark spots on the Al and there is hydrogen gas bubbling of it you can add all the P2NP solution at once to the Al+MeOH+HgCl2.  \n\n![g5.jpg](https://steemitimages.com/DQmVFXu6yscbvUpnJrFRF2hNfb8A8998fwtErZB4L8WEDVH/g5.jpg)\nA little later in the progress, the mixture gets darker and heats up even more to a mild reflux\n\n==============================================================================\n\n![g6.jpg](https://steemitimages.com/DQmST8fPyfDCUWdGBQp8DTuQox1j9wXzVMEanmckUeqxBkv/g6.jpg)\nBy now the mixture is dark and the aluminium is dissolving slowely, you can notice small shiny pieces of aluminium floating around, extra heat is applied here because the Al was so big that it reacted not fast enough, but hey better slow reaction than a volcano, right.  \n\n![g7.jpg](https://steemitimages.com/DQmQDdzBZFureDPSd12EWsghqDJ1M5bkG58BaUGGw7hx1bS/g7.jpg)\nNow when almost all the Al has dissolved add 200ml of cold water to the mixture to cool it down. Then basify it to pH 12 with 50g of NaOH dissolved in 150ml water. All the remaining Al will now react with the NaOH and form hydrogen gas and the mixture will heat up but not to a boil, that wouldn t matter though. \n\n==============================================================================\n\n![a1.jpg](https://steemitimages.com/DQmWbYm97hyWrNhfPcTBoiwtn6kSf4jSQNPArHguycQZpRn/a1.jpg)\n![a2.jpg](https://steemitimages.com/DQmPcYpn4CxJKEJopREhCfBMd7GjZynTqqDof9DEM7UFNxZ/a2.jpg)\n\nAfter all the washed this was collected in total.   Anhydrous magnesiumsulfate was added to suck up the water in their molecules and thus drying the ether and your product.  \nNow you only have to wait 12 hours to let the MgSO4 do it s work, filtrate it and then you can let the ether evaporate off at room temperature or with the help of a warm lamp. NOT AN OPEN FLAME!!! Ether is very inflammable.  \nAll the ether was evaporated off and 50ml anhydrous IPA was added to the amphetamine.freebase. Then to anhydrous IPA 98% sulfuric acid was added calculate how many mol amphetamine freebase you ve got and then take 90% of that and calculate how many mols of H2SO4 that represents and add that to 15ml of anhydrous IPA. Now drip H2SO4+IPA mix into the freebase which is dissolved in the IPA. Here you can see the crystals forming after a few drops have been added. \n\n![a3.jpg](https://steemitimages.com/DQmZjSv8N85rewNkgPyBz7d5SY8bEJyZ22QMTfFab7k3C43/a3.jpg)\n\n==============================================================================\n\n![a4.jpg](https://steemitimages.com/DQmPqzjBQdNVy35DobzRoj3C6KotUE4Q6aUwUAVqq9PSCny/a4.jpg)\nGlass full of crystals. It wasn t that much though but it looks like it is full of crystals. \n\n![a5.jpg](https://steemitimages.com/DQmbVUDoXPGgBqMLc3dCAoz1cV49xdX4WegzN4G19cWy7qj/a5.jpg)\nFiltrate it.\n\n![a6.jpg](https://steemitimages.com/DQmdonBD7WVoyujnVuaarTms8xSKfkWTMLbGgLBn7UBArXG/a6.jpg)\nAnd finally pure amphetamine sulfate has been obtained this was around 180mg. When only starting with 3,5g P2NP, when you loose 1g in the filter that is a lot, with bigger amounts yields are better anyway. \n\n==============================================================================\n\nThis was a complete amphetamine synthese.\n\n~neverless",
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}
2018/01/08 23:28:39
parent author
parent permlinkchemiacal
authorneverless
permlinka-complete-amphetamine-synthese
titleA Complete Amphetamine Synthese.
body![bild1.jpg](https://steemitimages.com/DQmZtYLErVcD3gJrDSDK7Bke14ycbANiFySUAXQtYB3NdNQ/bild1.jpg) This is everything you need for making P2NP, from left to right: Pipette-aparatus, several pipettes, dean&stark trap, PTFE greas, toluene, measuring cylinder 100ml, nitroethane, benzaldehyde, n-butylamine, above the brown flask a heating mantle and a 250ml RB-flask. The ratio s you should use are 1mol benzaldehyde and 1 mol nitroethane and 0,1mol R-NH2. Converting mols to ml s you will find out that you will need: SWIM didn t use 1 mol right away but first wanted to experiment with smaller amounts, so he used: 17ml benzaldehyde 13,3ml nitroethane 3,3ml n-butylamine 33ml toluene ============================================================================== Be sure that non of the products you use will contain water since when performing the reaction water will evolve which will be taken out of the reaction with the dean&stark trap because it prevents a good yield of P2NP. ![bild2.jpg](https://steemitimages.com/DQmURrkAdLg3Xj3Npq6c41K9LPfVRqn1WoF3VfU6CYcs7SS/bild2.jpg) All the chemicals mixed together. ![bild3.jpg](https://steemitimages.com/DQmd3RBEJZ4P6F5AX2R6NPKKdijjKiWQjxh9DTTm3XRBdwj/bild3.jpg) An overall view ============================================================================== ![bild4.jpg](https://steemitimages.com/DQmWw4pd8Sc9YZtLRNgMDaUvRUB6s2dYQmx8X9VjRB7CSW4/bild4.jpg) After heating it a bit to get it at 100*C aprox. ![bild5.jpg](https://steemitimages.com/DQmUNS6QovqforkZNgDytsjSMw8kDS5KzDerSpkYRzRdeS1/bild5.jpg) A vague picture of how it looks like after 3 hours of refluxing, if the color will get orange to dark orange before 6 hours you should stop refluxing at that time. But don t reflux it longer than 6 hours, sometimes you only need 3 hours though. To improve yield you can also add 1ml of glacial acetic acid to buffer the n-butylamine. For every mole of benzaldehyde one mole of water will form and since SWIM used 17ml of benzaldehyde which is ( 17ml x 1,05g/ml = 17,85g benzaldehyde / 106,12g/mol = ) 0,17mol benzaldehyde. Thus 0,17 mol of water will form which is ( 0,17 x 18,01 = ) 3,03ml of water. So after the 6 hours or earlier you should have 3,03ml of water in your trap, it will likely be more since your toluene will contain a bit of water too in SWIMS reaction he got 4ml of water. ============================================================================== ![bild6.jpg](https://steemitimages.com/DQmXB2RFKbBjT8XRDXoBvCxEq63iKTeEnFEyWbcU3ij9HfT/bild6.jpg) The color after 6 hours of refluxing and collecting 4ml of water in the trap. Now SWIM puts the round bottom flask in the freezer at 18*C because the P2NP is now dissolved in the toluene but when you will make the toluene very cold the P2NP won t dissolve in the toluene anymore or at least very bad. 7 hours later scratched the walls of the RB flask to initiate crystal forming. 10 hours later a lot of crystals in the RB flask, ![bild7.jpg](https://steemitimages.com/DQmeioX6nn5B7rnvzCP5TspnHrX6wz2UH2oPah2D414zpuk/bild7.jpg) The crop of crystals in the bottom of the flask. ============================================================================== ![bild8.jpg](https://steemitimages.com/DQmTgXbDXq9pTDp9H67hpFvTSTXRnmoarrZdqs3bjdEpZa6/bild8.jpg) Crystals formed on the sides. ![bild9.jpg](https://steemitimages.com/DQmWUGqfYmAi5CJYBqy9Y3hok7ZdcKDhXPfBgCdTVm8k1Hw/bild9.jpg) Now quickly break up the mass with a glass stir rod or a thermometer and throw the mixture threw a buchner filter (filtration under vacuum). The toluene will get back to room temperature and thus the crystals will dissolve back into the toluene that is why you need to be so quick and necesarilly do need to use a buchner filter. ============================================================================== ![bild10.jpg](https://steemitimages.com/DQmfKARNU4GUnye8LNpLTPZwXeguyrQHMbsE1HpnuUc52P3/bild10.jpg) Just a picture of the buchner filter how it looks like. Put the crystals on a paper to air-dry. As you can see the crystals are yellow coloured so they need purification or else your next product will be crap and yellow too. The first crop weighed 6,02 gram when completely dry. The second crop was 8,01gram SWIM evaporated off the half of the liquid and put it back in the fridge. ![bild11.jpg](https://steemitimages.com/DQmPzQiET1CTEZbq3f3C1weWTvKfjyA6kcjwUQihDxfG2Rv/bild11.jpg) Evaporating off the half of the toluene. ![bild12.jpg](https://steemitimages.com/DQmemD8GF5W6Dh4gsS4fKAoLJ4Qq9wUGHMNzCR45BAbpizV/bild12.jpg) Toluene and water seperated. ============================================================================== Now the crystals were purified by dissolving them in a minimal amount of boiling isopropylalcohol which is standing in a hot water bath, when they have all dissolved put a watch glass over the top of the erlenmyer and let them cool to room temperature; then put them in the deep freezer and vacuum filtrate them over a buchner filter and let them dry again. ![bild13.jpg](https://steemitimages.com/DQmZJAVYxyiso3a7x49i4XZtje3Qi12N3RiECFMSX78iP14/bild13.jpg) ![bild14.jpg](https://steemitimages.com/DQmcRhh9is4yenxSdZFnQVpoSQErDaQVa8vv2CPCFe1BZJf/bild14.jpg) Beaker with IPA standing in beaker with water. On the right the P2NP crystals. ![bild15.jpg](https://steemitimages.com/DQmTtDvyaZXL5uCavPfRwS5jqqSi7Uc8XXwg68rcWS5QCLD/bild15.jpg) ![bild16.jpg](https://steemitimages.com/DQma86bD6J1r3h7dVPMCnXL3B1xYtgfhNWxXynz8SKyQNcH/bild16.jpg) P2NP dissolved in boiling IPA. Cooling down, you can see crystals forming ![h1.jpg](https://steemitimages.com/DQmcDWBrPtYExYpZhJQzhvESfmXrjXz9JtEyaNb54UMbvzU/h1.jpg) ![h2.jpg](https://steemitimages.com/DQmXhJu28irCN27Cz6PsfKo6b7rFsYkQQkyRHUoaHskxpiP/h2.jpg) ![h3.jpg](https://steemitimages.com/DQmNWz3wHuQcDzw2yTHhFeLk3FpbzWqbbswtCg7MeyEJTka/h3.jpg) ![h4.jpg](https://steemitimages.com/DQmNQyiiLAZkDkjRdy2jk9oEGaCtWn5SY77A4gvwN8krEaW/h4.jpg) Here you can see the crystals forming while cooling down, in the buchner filter the crystals were washed with water. From the 14,03g of P2NP which SWIM started with 13,7g of P2NP was left over after the recrystalization/purification step. ============================================================================== Now it is time (by the mean time the P2NP is dry again ;-) ) to do the aminated reduction of the P2NP to amphetamine.freebase. This was first tested with 3,5g of P2NP: You will need 5g Al foil cut it into 1 (2,5cm) squares and then fold them up to nuggets and you should wrap them up so tight that you can only still press them a little with your fingers. ![g1.jpg](https://steemitimages.com/DQmPMTpQej9yE623D1qRfroNvzeccKSZt8NukN62vRP8VpK/g1.jpg) This is the reflux setup that SWIM will be using. ![g2.jpg](https://steemitimages.com/DQmPEHgHce3wE1FdeUtzt8T8S7x9eoMmqDmAQM37xFTWaSs/g2.jpg) Close up and methanol added which had 70mg of HgCl2 dissolved in it As sayd above at the picture you will need a solvent like methanol and you dissolve HgCl2 inside the solvent and add it to the Aluminium make sure the aluminium is not too fine else a very heavy reaction will occur with the possibilty that mercury and hydrochloric acid, boiling methanol and hot aluminium will cover you like a vulcano. The HgCl2 can also be substituted by other Hg salts like Hg(NO3)2. ============================================================================== After 10min average the Al will start to evolve hydrogen gas, depending on thickness of the foil. If you use thin foil wrap it up 3-4 layers before cuting squares out of it else it will react too heavily. ![g3.jpg](https://steemitimages.com/DQmNy4TZMhHs8CPqQAHK8j4eH12tgAzRVcwRx8qhfjZ6u2g/g3.jpg) The methanol will become gray/blue, and the aluminium will become less shiny. On for hand you should make a solution of your P2NP that will be added to the mixture later on. The solvent used was isopropylalcohol and glacial acetic acid, in a ratio: 40ml IPA; 60ml GAA; 3,5g P2NP You might need to heat it up because the P2NP will not dissolve easily at room temperature. ============================================================================== ![g4.jpg](https://steemitimages.com/DQmbLq3Bty1V6SQs4bzVPSZ67iJ42TX7v7AosPnvhoDGag1/g4.jpg) The reaction will heat up and when there are dark spots on the Al and there is hydrogen gas bubbling of it you can add all the P2NP solution at once to the Al+MeOH+HgCl2. ![g5.jpg](https://steemitimages.com/DQmVFXu6yscbvUpnJrFRF2hNfb8A8998fwtErZB4L8WEDVH/g5.jpg) A little later in the progress, the mixture gets darker and heats up even more to a mild reflux ============================================================================== ![g6.jpg](https://steemitimages.com/DQmST8fPyfDCUWdGBQp8DTuQox1j9wXzVMEanmckUeqxBkv/g6.jpg) By now the mixture is dark and the aluminium is dissolving slowely, you can notice small shiny pieces of aluminium floating around, extra heat is applied here because the Al was so big that it reacted not fast enough, but hey better slow reaction than a volcano, right. ![g7.jpg](https://steemitimages.com/DQmQDdzBZFureDPSd12EWsghqDJ1M5bkG58BaUGGw7hx1bS/g7.jpg) Now when almost all the Al has dissolved add 200ml of cold water to the mixture to cool it down. Then basify it to pH 12 with 50g of NaOH dissolved in 150ml water. All the remaining Al will now react with the NaOH and form hydrogen gas and the mixture will heat up but not to a boil, that wouldn t matter though. ============================================================================== ![a1.jpg](https://steemitimages.com/DQmWbYm97hyWrNhfPcTBoiwtn6kSf4jSQNPArHguycQZpRn/a1.jpg) ![a2.jpg](https://steemitimages.com/DQmPcYpn4CxJKEJopREhCfBMd7GjZynTqqDof9DEM7UFNxZ/a2.jpg) After all the washed this was collected in total. Anhydrous magnesiumsulfate was added to suck up the water in their molecules and thus drying the ether and your product. Now you only have to wait 12 hours to let the MgSO4 do it s work, filtrate it and then you can let the ether evaporate off at room temperature or with the help of a warm lamp. NOT AN OPEN FLAME!!! Ether is very inflammable. All the ether was evaporated off and 50ml anhydrous IPA was added to the amphetamine.freebase. Then to anhydrous IPA 98% sulfuric acid was added calculate how many mol amphetamine freebase you ve got and then take 90% of that and calculate how many mols of H2SO4 that represents and add that to 15ml of anhydrous IPA. Now drip H2SO4+IPA mix into the freebase which is dissolved in the IPA. Here you can see the crystals forming after a few drops have been added. ![a3.jpg](https://steemitimages.com/DQmZjSv8N85rewNkgPyBz7d5SY8bEJyZ22QMTfFab7k3C43/a3.jpg) ============================================================================== ![a4.jpg](https://steemitimages.com/DQmPqzjBQdNVy35DobzRoj3C6KotUE4Q6aUwUAVqq9PSCny/a4.jpg) Glass full of crystals. It wasn t that much though but it looks like it is full of crystals. ![a5.jpg](https://steemitimages.com/DQmbVUDoXPGgBqMLc3dCAoz1cV49xdX4WegzN4G19cWy7qj/a5.jpg) Filtrate it. ![a6.jpg](https://steemitimages.com/DQmdonBD7WVoyujnVuaarTms8xSKfkWTMLbGgLBn7UBArXG/a6.jpg) And finally pure amphetamine sulfate has been obtained this was around 180mg. When only starting with 3,5g P2NP, when you loose 1g in the filter that is a lot, with bigger amounts yields are better anyway. ============================================================================== This was a complete amphetamine synthese. ~neverless
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Transaction InfoBlock #18810987/Trx dc9e659d8c8536e00a08a10eb39918855b557a83
View Raw JSON Data
{
  "trx_id": "dc9e659d8c8536e00a08a10eb39918855b557a83",
  "block": 18810987,
  "trx_in_block": 32,
  "op_in_trx": 0,
  "virtual_op": 0,
  "timestamp": "2018-01-08T23:28:39",
  "op": [
    "comment",
    {
      "parent_author": "",
      "parent_permlink": "chemiacal",
      "author": "neverless",
      "permlink": "a-complete-amphetamine-synthese",
      "title": "A Complete Amphetamine Synthese.",
      "body": "![bild1.jpg](https://steemitimages.com/DQmZtYLErVcD3gJrDSDK7Bke14ycbANiFySUAXQtYB3NdNQ/bild1.jpg)\n\n\nThis is everything you need for making P2NP, from left to right: Pipette-aparatus, several pipettes, dean&stark trap, PTFE greas, toluene, measuring cylinder 100ml, nitroethane, benzaldehyde, n-butylamine, above the brown flask a heating mantle and a 250ml RB-flask.  \n\nThe ratio s you should use are 1mol benzaldehyde and 1 mol nitroethane and 0,1mol R-NH2. Converting mols to ml s you will find out that you will need: SWIM didn t use 1 mol right away but first wanted to experiment with smaller amounts, so he used: \n\n17ml benzaldehyde  13,3ml nitroethane  3,3ml n-butylamine 33ml toluene  \n\n==============================================================================\n\nBe sure that non of the products you use will contain water since when performing the reaction water will evolve which will be taken out of the reaction with the dean&stark trap because it prevents a good yield of P2NP.  \n\n![bild2.jpg](https://steemitimages.com/DQmURrkAdLg3Xj3Npq6c41K9LPfVRqn1WoF3VfU6CYcs7SS/bild2.jpg)\nAll the chemicals mixed together.\n\n![bild3.jpg](https://steemitimages.com/DQmd3RBEJZ4P6F5AX2R6NPKKdijjKiWQjxh9DTTm3XRBdwj/bild3.jpg)\nAn overall view \n\n==============================================================================\n\n![bild4.jpg](https://steemitimages.com/DQmWw4pd8Sc9YZtLRNgMDaUvRUB6s2dYQmx8X9VjRB7CSW4/bild4.jpg)\nAfter heating it a bit to get it at 100*C aprox.  \n\n![bild5.jpg](https://steemitimages.com/DQmUNS6QovqforkZNgDytsjSMw8kDS5KzDerSpkYRzRdeS1/bild5.jpg)\n\nA vague picture of how it looks like after 3 hours of refluxing, if the color will get orange to dark orange before 6 hours you should stop refluxing at that time. But don t reflux it longer than 6 hours, sometimes you only need 3 hours though. To improve yield you can also add 1ml of glacial acetic acid to buffer the n-butylamine. For every mole of benzaldehyde one mole of water will form and since SWIM used 17ml of benzaldehyde which is ( 17ml x 1,05g/ml = 17,85g benzaldehyde / 106,12g/mol = ) 0,17mol benzaldehyde. Thus 0,17 mol of water will form which is ( 0,17 x 18,01 = ) 3,03ml of water. So after the 6 hours or earlier you should have 3,03ml of water in your trap, it will likely be more since your toluene will contain a bit of water too in SWIMS reaction he got 4ml of water.     \n\n==============================================================================\n\n![bild6.jpg](https://steemitimages.com/DQmXB2RFKbBjT8XRDXoBvCxEq63iKTeEnFEyWbcU3ij9HfT/bild6.jpg)\n\nThe color after 6 hours of refluxing and collecting 4ml of water in the trap. Now SWIM puts the round bottom flask in the freezer at 18*C because the P2NP is now dissolved in the toluene but when you will make the toluene very cold the P2NP won t dissolve in the toluene anymore or at least very bad.  \n7 hours later scratched the walls of the RB flask to initiate crystal forming. 10 hours later a lot of crystals in the RB flask, \n\n![bild7.jpg](https://steemitimages.com/DQmeioX6nn5B7rnvzCP5TspnHrX6wz2UH2oPah2D414zpuk/bild7.jpg)\nThe crop of crystals in the bottom of the flask. \n\n==============================================================================\n\n![bild8.jpg](https://steemitimages.com/DQmTgXbDXq9pTDp9H67hpFvTSTXRnmoarrZdqs3bjdEpZa6/bild8.jpg)\nCrystals formed on the sides. \n\n![bild9.jpg](https://steemitimages.com/DQmWUGqfYmAi5CJYBqy9Y3hok7ZdcKDhXPfBgCdTVm8k1Hw/bild9.jpg)\n\nNow quickly break up the mass with a glass stir rod or a thermometer and throw the mixture threw a buchner filter (filtration under vacuum). The toluene will get back to room temperature and thus the crystals will dissolve back into the toluene that is why you need to be so quick and necesarilly do need to use a buchner filter. \n\n==============================================================================\n\n\n![bild10.jpg](https://steemitimages.com/DQmfKARNU4GUnye8LNpLTPZwXeguyrQHMbsE1HpnuUc52P3/bild10.jpg)\nJust a picture of the buchner filter how it looks like. Put the crystals on a paper to air-dry.  \nAs you can see the crystals are yellow coloured so they need purification or else your next product will be crap and yellow too. The first crop weighed 6,02 gram when completely dry. The second crop was 8,01gram SWIM evaporated off the half of the liquid and put it back in the fridge.\n\n![bild11.jpg](https://steemitimages.com/DQmPzQiET1CTEZbq3f3C1weWTvKfjyA6kcjwUQihDxfG2Rv/bild11.jpg)\nEvaporating off the half of the toluene. \n![bild12.jpg](https://steemitimages.com/DQmemD8GF5W6Dh4gsS4fKAoLJ4Qq9wUGHMNzCR45BAbpizV/bild12.jpg)\n Toluene and water seperated.\n\n==============================================================================\n\n Now the crystals were purified by dissolving them in a minimal amount of boiling isopropylalcohol which is standing in a hot water bath, when they have all dissolved put a watch glass over the top of the erlenmyer and let them cool to room temperature; then put them in the deep freezer and vacuum filtrate them over a buchner filter and let them dry again.\n![bild13.jpg](https://steemitimages.com/DQmZJAVYxyiso3a7x49i4XZtje3Qi12N3RiECFMSX78iP14/bild13.jpg)\n![bild14.jpg](https://steemitimages.com/DQmcRhh9is4yenxSdZFnQVpoSQErDaQVa8vv2CPCFe1BZJf/bild14.jpg)\nBeaker with IPA standing in beaker with water. On the right the P2NP crystals.\n\n![bild15.jpg](https://steemitimages.com/DQmTtDvyaZXL5uCavPfRwS5jqqSi7Uc8XXwg68rcWS5QCLD/bild15.jpg)\n![bild16.jpg](https://steemitimages.com/DQma86bD6J1r3h7dVPMCnXL3B1xYtgfhNWxXynz8SKyQNcH/bild16.jpg)\nP2NP dissolved in boiling IPA.            Cooling down, you can see crystals forming\n\n\n![h1.jpg](https://steemitimages.com/DQmcDWBrPtYExYpZhJQzhvESfmXrjXz9JtEyaNb54UMbvzU/h1.jpg)\n![h2.jpg](https://steemitimages.com/DQmXhJu28irCN27Cz6PsfKo6b7rFsYkQQkyRHUoaHskxpiP/h2.jpg)\n![h3.jpg](https://steemitimages.com/DQmNWz3wHuQcDzw2yTHhFeLk3FpbzWqbbswtCg7MeyEJTka/h3.jpg)\n![h4.jpg](https://steemitimages.com/DQmNQyiiLAZkDkjRdy2jk9oEGaCtWn5SY77A4gvwN8krEaW/h4.jpg)\nHere you can see the crystals forming while cooling down, in the buchner filter the crystals were washed with water.  \nFrom the 14,03g of P2NP which SWIM started with 13,7g of P2NP was left over after the recrystalization/purification step. \n\n==============================================================================\n\n Now it is time (by the mean time the P2NP is dry again ;-) ) to do the aminated reduction of the P2NP to amphetamine.freebase.  \nThis was first tested with 3,5g of P2NP:  \nYou will need 5g Al foil cut it into 1 (2,5cm) squares and then fold them up to nuggets and you should wrap them up so tight that you can only still press them a little with your fingers.\n\n![g1.jpg](https://steemitimages.com/DQmPMTpQej9yE623D1qRfroNvzeccKSZt8NukN62vRP8VpK/g1.jpg)\nThis is the reflux setup that SWIM will be using. \n![g2.jpg](https://steemitimages.com/DQmPEHgHce3wE1FdeUtzt8T8S7x9eoMmqDmAQM37xFTWaSs/g2.jpg)\n Close up and methanol added which had 70mg of HgCl2 dissolved in it\n\nAs sayd above at the picture you will need a solvent like methanol and you dissolve HgCl2 inside the solvent and add it to the Aluminium make sure the aluminium is not too fine else a very heavy reaction will occur with the possibilty that mercury and hydrochloric acid, boiling methanol and hot aluminium will cover you like a vulcano. The HgCl2 can also be substituted by other Hg salts like Hg(NO3)2. \n\n==============================================================================\n\nAfter 10min average the Al will start to evolve hydrogen gas, depending on thickness of the foil. If you use thin foil wrap it up 3-4 layers before cuting squares out of it else it will react too heavily. \n\n![g3.jpg](https://steemitimages.com/DQmNy4TZMhHs8CPqQAHK8j4eH12tgAzRVcwRx8qhfjZ6u2g/g3.jpg)\nThe methanol will become gray/blue, and the aluminium will become less shiny. \n\nOn for hand you should make a solution of your P2NP that will be added to the mixture later on. The solvent used was isopropylalcohol and glacial acetic acid, in a ratio:\n\n 40ml IPA; 60ml GAA; 3,5g P2NP\n\nYou might need to heat it up because the P2NP will not dissolve easily at room temperature.\n\n==============================================================================\n\n![g4.jpg](https://steemitimages.com/DQmbLq3Bty1V6SQs4bzVPSZ67iJ42TX7v7AosPnvhoDGag1/g4.jpg)\nThe reaction will heat up and when there are dark spots on the Al and there is hydrogen gas bubbling of it you can add all the P2NP solution at once to the Al+MeOH+HgCl2.  \n\n![g5.jpg](https://steemitimages.com/DQmVFXu6yscbvUpnJrFRF2hNfb8A8998fwtErZB4L8WEDVH/g5.jpg)\nA little later in the progress, the mixture gets darker and heats up even more to a mild reflux\n\n==============================================================================\n\n![g6.jpg](https://steemitimages.com/DQmST8fPyfDCUWdGBQp8DTuQox1j9wXzVMEanmckUeqxBkv/g6.jpg)\nBy now the mixture is dark and the aluminium is dissolving slowely, you can notice small shiny pieces of aluminium floating around, extra heat is applied here because the Al was so big that it reacted not fast enough, but hey better slow reaction than a volcano, right.  \n\n![g7.jpg](https://steemitimages.com/DQmQDdzBZFureDPSd12EWsghqDJ1M5bkG58BaUGGw7hx1bS/g7.jpg)\nNow when almost all the Al has dissolved add 200ml of cold water to the mixture to cool it down. Then basify it to pH 12 with 50g of NaOH dissolved in 150ml water. All the remaining Al will now react with the NaOH and form hydrogen gas and the mixture will heat up but not to a boil, that wouldn t matter though. \n\n==============================================================================\n\n![a1.jpg](https://steemitimages.com/DQmWbYm97hyWrNhfPcTBoiwtn6kSf4jSQNPArHguycQZpRn/a1.jpg)\n![a2.jpg](https://steemitimages.com/DQmPcYpn4CxJKEJopREhCfBMd7GjZynTqqDof9DEM7UFNxZ/a2.jpg)\n\nAfter all the washed this was collected in total.   Anhydrous magnesiumsulfate was added to suck up the water in their molecules and thus drying the ether and your product.  \nNow you only have to wait 12 hours to let the MgSO4 do it s work, filtrate it and then you can let the ether evaporate off at room temperature or with the help of a warm lamp. NOT AN OPEN FLAME!!! Ether is very inflammable.  \nAll the ether was evaporated off and 50ml anhydrous IPA was added to the amphetamine.freebase. Then to anhydrous IPA 98% sulfuric acid was added calculate how many mol amphetamine freebase you ve got and then take 90% of that and calculate how many mols of H2SO4 that represents and add that to 15ml of anhydrous IPA. Now drip H2SO4+IPA mix into the freebase which is dissolved in the IPA. Here you can see the crystals forming after a few drops have been added. \n\n![a3.jpg](https://steemitimages.com/DQmZjSv8N85rewNkgPyBz7d5SY8bEJyZ22QMTfFab7k3C43/a3.jpg)\n\n==============================================================================\n\n![a4.jpg](https://steemitimages.com/DQmPqzjBQdNVy35DobzRoj3C6KotUE4Q6aUwUAVqq9PSCny/a4.jpg)\nGlass full of crystals. It wasn t that much though but it looks like it is full of crystals. \n\n![a5.jpg](https://steemitimages.com/DQmbVUDoXPGgBqMLc3dCAoz1cV49xdX4WegzN4G19cWy7qj/a5.jpg)\nFiltrate it.\n\n![a6.jpg](https://steemitimages.com/DQmdonBD7WVoyujnVuaarTms8xSKfkWTMLbGgLBn7UBArXG/a6.jpg)\nAnd finally pure amphetamine sulfate has been obtained this was around 180mg. When only starting with 3,5g P2NP, when you loose 1g in the filter that is a lot, with bigger amounts yields are better anyway. \n\n==============================================================================\n\nThis was a complete amphetamine synthese.\n\n~neverless",
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2018/01/08 23:25:51
parent author
parent permlinkchemiacal
authorneverless
permlinka-complete-amphetamine-synthese
titleA Complete Amphetamine Synthese.
body![bild1.jpg](https://steemitimages.com/DQmZtYLErVcD3gJrDSDK7Bke14ycbANiFySUAXQtYB3NdNQ/bild1.jpg) This is everything you need for making P2NP, from left to right: Pipette-aparatus, several pipettes, dean&stark trap, PTFE greas, toluene, measuring cylinder 100ml, nitroethane, benzaldehyde, n-butylamine, above the brown flask a heating mantle and a 250ml RB-flask. The ratio s you should use are 1mol benzaldehyde and 1 mol nitroethane and 0,1mol R-NH2. Converting mols to ml s you will find out that you will need: SWIM didn t use 1 mol right away but first wanted to experiment with smaller amounts, so he used: 17ml benzaldehyde 13,3ml nitroethane 3,3ml n-butylamine 33ml toluene ============================================================================== Be sure that non of the products you use will contain water since when performing the reaction water will evolve which will be taken out of the reaction with the dean&stark trap because it prevents a good yield of P2NP. ![bild2.jpg](https://steemitimages.com/DQmURrkAdLg3Xj3Npq6c41K9LPfVRqn1WoF3VfU6CYcs7SS/bild2.jpg) All the chemicals mixed together. ![bild3.jpg](https://steemitimages.com/DQmd3RBEJZ4P6F5AX2R6NPKKdijjKiWQjxh9DTTm3XRBdwj/bild3.jpg) An overall view ============================================================================== ![bild4.jpg](https://steemitimages.com/DQmWw4pd8Sc9YZtLRNgMDaUvRUB6s2dYQmx8X9VjRB7CSW4/bild4.jpg) After heating it a bit to get it at 100*C aprox. ![bild5.jpg](https://steemitimages.com/DQmUNS6QovqforkZNgDytsjSMw8kDS5KzDerSpkYRzRdeS1/bild5.jpg) A vague picture of how it looks like after 3 hours of refluxing, if the color will get orange to dark orange before 6 hours you should stop refluxing at that time. But don t reflux it longer than 6 hours, sometimes you only need 3 hours though. To improve yield you can also add 1ml of glacial acetic acid to buffer the n-butylamine. For every mole of benzaldehyde one mole of water will form and since SWIM used 17ml of benzaldehyde which is ( 17ml x 1,05g/ml = 17,85g benzaldehyde / 106,12g/mol = ) 0,17mol benzaldehyde. Thus 0,17 mol of water will form which is ( 0,17 x 18,01 = ) 3,03ml of water. So after the 6 hours or earlier you should have 3,03ml of water in your trap, it will likely be more since your toluene will contain a bit of water too in SWIMS reaction he got 4ml of water. ============================================================================== ![bild6.jpg](https://steemitimages.com/DQmXB2RFKbBjT8XRDXoBvCxEq63iKTeEnFEyWbcU3ij9HfT/bild6.jpg) The color after 6 hours of refluxing and collecting 4ml of water in the trap. Now SWIM puts the round bottom flask in the freezer at 18*C because the P2NP is now dissolved in the toluene but when you will make the toluene very cold the P2NP won t dissolve in the toluene anymore or at least very bad. 7 hours later scratched the walls of the RB flask to initiate crystal forming. 10 hours later a lot of crystals in the RB flask, ![bild7.jpg](https://steemitimages.com/DQmeioX6nn5B7rnvzCP5TspnHrX6wz2UH2oPah2D414zpuk/bild7.jpg) The crop of crystals in the bottom of the flask. ============================================================================== ![bild8.jpg](https://steemitimages.com/DQmTgXbDXq9pTDp9H67hpFvTSTXRnmoarrZdqs3bjdEpZa6/bild8.jpg) Crystals formed on the sides. ![bild9.jpg](https://steemitimages.com/DQmWUGqfYmAi5CJYBqy9Y3hok7ZdcKDhXPfBgCdTVm8k1Hw/bild9.jpg) Now quickly break up the mass with a glass stir rod or a thermometer and throw the mixture threw a buchner filter (filtration under vacuum). The toluene will get back to room temperature and thus the crystals will dissolve back into the toluene that is why you need to be so quick and necesarilly do need to use a buchner filter. ============================================================================== ![bild10.jpg](https://steemitimages.com/DQmfKARNU4GUnye8LNpLTPZwXeguyrQHMbsE1HpnuUc52P3/bild10.jpg) Just a picture of the buchner filter how it looks like. Put the crystals on a paper to air-dry. As you can see the crystals are yellow coloured so they need purification or else your next product will be crap and yellow too. The first crop weighed 6,02 gram when completely dry. The second crop was 8,01gram SWIM evaporated off the half of the liquid and put it back in the fridge. ![bild11.jpg](https://steemitimages.com/DQmPzQiET1CTEZbq3f3C1weWTvKfjyA6kcjwUQihDxfG2Rv/bild11.jpg) Evaporating off the half of the toluene. ![bild12.jpg](https://steemitimages.com/DQmemD8GF5W6Dh4gsS4fKAoLJ4Qq9wUGHMNzCR45BAbpizV/bild12.jpg) Toluene and water seperated. ============================================================================== Now the crystals were purified by dissolving them in a minimal amount of boiling isopropylalcohol which is standing in a hot water bath, when they have all dissolved put a watch glass over the top of the erlenmyer and let them cool to room temperature; then put them in the deep freezer and vacuum filtrate them over a buchner filter and let them dry again. ![bild13.jpg](https://steemitimages.com/DQmZJAVYxyiso3a7x49i4XZtje3Qi12N3RiECFMSX78iP14/bild13.jpg) ![bild14.jpg](https://steemitimages.com/DQmcRhh9is4yenxSdZFnQVpoSQErDaQVa8vv2CPCFe1BZJf/bild14.jpg) Beaker with IPA standing in beaker with water. On the right the P2NP crystals. ![bild15.jpg](https://steemitimages.com/DQmTtDvyaZXL5uCavPfRwS5jqqSi7Uc8XXwg68rcWS5QCLD/bild15.jpg) ![bild16.jpg](https://steemitimages.com/DQma86bD6J1r3h7dVPMCnXL3B1xYtgfhNWxXynz8SKyQNcH/bild16.jpg) P2NP dissolved in boiling IPA. Cooling down, you can see crystals forming ![h1.jpg](https://steemitimages.com/DQmcDWBrPtYExYpZhJQzhvESfmXrjXz9JtEyaNb54UMbvzU/h1.jpg) ![h2.jpg](https://steemitimages.com/DQmXhJu28irCN27Cz6PsfKo6b7rFsYkQQkyRHUoaHskxpiP/h2.jpg) ![h3.jpg](https://steemitimages.com/DQmNWz3wHuQcDzw2yTHhFeLk3FpbzWqbbswtCg7MeyEJTka/h3.jpg) ![h4.jpg](https://steemitimages.com/DQmNQyiiLAZkDkjRdy2jk9oEGaCtWn5SY77A4gvwN8krEaW/h4.jpg) Here you can see the crystals forming while cooling down, in the buchner filter the crystals were washed with water. From the 14,03g of P2NP which SWIM started with 13,7g of P2NP was left over after the recrystalization/purification step. ============================================================================== Now it is time (by the mean time the P2NP is dry again ;-) ) to do the aminated reduction of the P2NP to amphetamine.freebase. This was first tested with 3,5g of P2NP: You will need 5g Al foil cut it into 1 (2,5cm) squares and then fold them up to nuggets and you should wrap them up so tight that you can only still press them a little with your fingers. ![g1.jpg](https://steemitimages.com/DQmPMTpQej9yE623D1qRfroNvzeccKSZt8NukN62vRP8VpK/g1.jpg) This is the reflux setup that SWIM will be using. ![g2.jpg](https://steemitimages.com/DQmPEHgHce3wE1FdeUtzt8T8S7x9eoMmqDmAQM37xFTWaSs/g2.jpg) Close up and methanol added which had 70mg of HgCl2 dissolved in it As sayd above at the picture you will need a solvent like methanol and you dissolve HgCl2 inside the solvent and add it to the Aluminium make sure the aluminium is not too fine else a very heavy reaction will occur with the possibilty that mercury and hydrochloric acid, boiling methanol and hot aluminium will cover you like a vulcano. The HgCl2 can also be substituted by other Hg salts like Hg(NO3)2. ============================================================================== After 10min average the Al will start to evolve hydrogen gas, depending on thickness of the foil. If you use thin foil wrap it up 3-4 layers before cuting squares out of it else it will react too heavily. ![g3.jpg](https://steemitimages.com/DQmNy4TZMhHs8CPqQAHK8j4eH12tgAzRVcwRx8qhfjZ6u2g/g3.jpg) The methanol will become gray/blue, and the aluminium will become less shiny. On for hand you should make a solution of your P2NP that will be added to the mixture later on. The solvent used was isopropylalcohol and glacial acetic acid, in a ratio: 40ml IPA; 60ml GAA; 3,5g P2NP You might need to heat it up because the P2NP will not dissolve easily at room temperature. ============================================================================== ![g4.jpg](https://steemitimages.com/DQmbLq3Bty1V6SQs4bzVPSZ67iJ42TX7v7AosPnvhoDGag1/g4.jpg) The reaction will heat up and when there are dark spots on the Al and there is hydrogen gas bubbling of it you can add all the P2NP solution at once to the Al+MeOH+HgCl2. ![g5.jpg](https://steemitimages.com/DQmVFXu6yscbvUpnJrFRF2hNfb8A8998fwtErZB4L8WEDVH/g5.jpg) A little later in the progress, the mixture gets darker and heats up even more to a mild reflux ============================================================================== ![g6.jpg](https://steemitimages.com/DQmST8fPyfDCUWdGBQp8DTuQox1j9wXzVMEanmckUeqxBkv/g6.jpg) By now the mixture is dark and the aluminium is dissolving slowely, you can notice small shiny pieces of aluminium floating around, extra heat is applied here because the Al was so big that it reacted not fast enough, but hey better slow reaction than a volcano, right. ![g7.jpg](https://steemitimages.com/DQmQDdzBZFureDPSd12EWsghqDJ1M5bkG58BaUGGw7hx1bS/g7.jpg) Now when almost all the Al has dissolved add 200ml of cold water to the mixture to cool it down. Then basify it to pH 12 with 50g of NaOH dissolved in 150ml water. All the remaining Al will now react with the NaOH and form hydrogen gas and the mixture will heat up but not to a boil, that wouldn t matter though. ============================================================================== ![a1.jpg](https://steemitimages.com/DQmWbYm97hyWrNhfPcTBoiwtn6kSf4jSQNPArHguycQZpRn/a1.jpg) ![a2.jpg](https://steemitimages.com/DQmPcYpn4CxJKEJopREhCfBMd7GjZynTqqDof9DEM7UFNxZ/a2.jpg) After all the washed this was collected in total. Anhydrous magnesiumsulfate was added to suck up the water in their molecules and thus drying the ether and your product. Now you only have to wait 12 hours to let the MgSO4 do it s work, filtrate it and then you can let the ether evaporate off at room temperature or with the help of a warm lamp. NOT AN OPEN FLAME!!! Ether is very inflammable. All the ether was evaporated off and 50ml anhydrous IPA was added to the amphetamine.freebase. Then to anhydrous IPA 98% sulfuric acid was added calculate how many mol amphetamine freebase you ve got and then take 90% of that and calculate how many mols of H2SO4 that represents and add that to 15ml of anhydrous IPA. Now drip H2SO4+IPA mix into the freebase which is dissolved in the IPA. Here you can see the crystals forming after a few drops have been added. ![a3.jpg](https://steemitimages.com/DQmZjSv8N85rewNkgPyBz7d5SY8bEJyZ22QMTfFab7k3C43/a3.jpg) ============================================================================== ![a4.jpg](https://steemitimages.com/DQmPqzjBQdNVy35DobzRoj3C6KotUE4Q6aUwUAVqq9PSCny/a4.jpg) Glass full of crystals. It wasn t that much though but it looks like it is full of crystals. ![a5.jpg](https://steemitimages.com/DQmbVUDoXPGgBqMLc3dCAoz1cV49xdX4WegzN4G19cWy7qj/a5.jpg) Filtrate it. ![a6.jpg](https://steemitimages.com/DQmdonBD7WVoyujnVuaarTms8xSKfkWTMLbGgLBn7UBArXG/a6.jpg) And finally pure amphetamine sulfate has been obtained this was around 180mg. When only starting with 3,5g P2NP, when you loose 1g in the filter that is a lot, with bigger amounts yields are better anyway. ============================================================================== This was a complete amphetamine synthese. ~neverless
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Transaction InfoBlock #18810931/Trx 487877ef62dc1796be95a80cb3ca138ad8f1dc09
View Raw JSON Data
{
  "trx_id": "487877ef62dc1796be95a80cb3ca138ad8f1dc09",
  "block": 18810931,
  "trx_in_block": 48,
  "op_in_trx": 0,
  "virtual_op": 0,
  "timestamp": "2018-01-08T23:25:51",
  "op": [
    "comment",
    {
      "parent_author": "",
      "parent_permlink": "chemiacal",
      "author": "neverless",
      "permlink": "a-complete-amphetamine-synthese",
      "title": "A Complete Amphetamine Synthese.",
      "body": "![bild1.jpg](https://steemitimages.com/DQmZtYLErVcD3gJrDSDK7Bke14ycbANiFySUAXQtYB3NdNQ/bild1.jpg)\n\n\nThis is everything you need for making P2NP, from left to right: Pipette-aparatus, several pipettes, dean&stark trap, PTFE greas, toluene, measuring cylinder 100ml, nitroethane, benzaldehyde, n-butylamine, above the brown flask a heating mantle and a 250ml RB-flask.  \n\nThe ratio s you should use are 1mol benzaldehyde and 1 mol nitroethane and 0,1mol R-NH2. Converting mols to ml s you will find out that you will need: SWIM didn t use 1 mol right away but first wanted to experiment with smaller amounts, so he used: \n\n17ml benzaldehyde  13,3ml nitroethane  3,3ml n-butylamine 33ml toluene  \n\n==============================================================================\n\nBe sure that non of the products you use will contain water since when performing the reaction water will evolve which will be taken out of the reaction with the dean&stark trap because it prevents a good yield of P2NP.  \n\n![bild2.jpg](https://steemitimages.com/DQmURrkAdLg3Xj3Npq6c41K9LPfVRqn1WoF3VfU6CYcs7SS/bild2.jpg)\nAll the chemicals mixed together.\n\n![bild3.jpg](https://steemitimages.com/DQmd3RBEJZ4P6F5AX2R6NPKKdijjKiWQjxh9DTTm3XRBdwj/bild3.jpg)\nAn overall view \n\n==============================================================================\n\n![bild4.jpg](https://steemitimages.com/DQmWw4pd8Sc9YZtLRNgMDaUvRUB6s2dYQmx8X9VjRB7CSW4/bild4.jpg)\nAfter heating it a bit to get it at 100*C aprox.  \n\n![bild5.jpg](https://steemitimages.com/DQmUNS6QovqforkZNgDytsjSMw8kDS5KzDerSpkYRzRdeS1/bild5.jpg)\n\nA vague picture of how it looks like after 3 hours of refluxing, if the color will get orange to dark orange before 6 hours you should stop refluxing at that time. But don t reflux it longer than 6 hours, sometimes you only need 3 hours though. To improve yield you can also add 1ml of glacial acetic acid to buffer the n-butylamine. For every mole of benzaldehyde one mole of water will form and since SWIM used 17ml of benzaldehyde which is ( 17ml x 1,05g/ml = 17,85g benzaldehyde / 106,12g/mol = ) 0,17mol benzaldehyde. Thus 0,17 mol of water will form which is ( 0,17 x 18,01 = ) 3,03ml of water. So after the 6 hours or earlier you should have 3,03ml of water in your trap, it will likely be more since your toluene will contain a bit of water too in SWIMS reaction he got 4ml of water.     \n\n==============================================================================\n\n![bild6.jpg](https://steemitimages.com/DQmXB2RFKbBjT8XRDXoBvCxEq63iKTeEnFEyWbcU3ij9HfT/bild6.jpg)\n\nThe color after 6 hours of refluxing and collecting 4ml of water in the trap. Now SWIM puts the round bottom flask in the freezer at 18*C because the P2NP is now dissolved in the toluene but when you will make the toluene very cold the P2NP won t dissolve in the toluene anymore or at least very bad.  \n7 hours later scratched the walls of the RB flask to initiate crystal forming. 10 hours later a lot of crystals in the RB flask, \n\n![bild7.jpg](https://steemitimages.com/DQmeioX6nn5B7rnvzCP5TspnHrX6wz2UH2oPah2D414zpuk/bild7.jpg)\nThe crop of crystals in the bottom of the flask. \n\n==============================================================================\n\n![bild8.jpg](https://steemitimages.com/DQmTgXbDXq9pTDp9H67hpFvTSTXRnmoarrZdqs3bjdEpZa6/bild8.jpg)\nCrystals formed on the sides. \n\n![bild9.jpg](https://steemitimages.com/DQmWUGqfYmAi5CJYBqy9Y3hok7ZdcKDhXPfBgCdTVm8k1Hw/bild9.jpg)\n\nNow quickly break up the mass with a glass stir rod or a thermometer and throw the mixture threw a buchner filter (filtration under vacuum). The toluene will get back to room temperature and thus the crystals will dissolve back into the toluene that is why you need to be so quick and necesarilly do need to use a buchner filter. \n\n==============================================================================\n\n\n![bild10.jpg](https://steemitimages.com/DQmfKARNU4GUnye8LNpLTPZwXeguyrQHMbsE1HpnuUc52P3/bild10.jpg)\nJust a picture of the buchner filter how it looks like. Put the crystals on a paper to air-dry.  \nAs you can see the crystals are yellow coloured so they need purification or else your next product will be crap and yellow too. The first crop weighed 6,02 gram when completely dry. The second crop was 8,01gram SWIM evaporated off the half of the liquid and put it back in the fridge.\n\n![bild11.jpg](https://steemitimages.com/DQmPzQiET1CTEZbq3f3C1weWTvKfjyA6kcjwUQihDxfG2Rv/bild11.jpg)\nEvaporating off the half of the toluene. \n![bild12.jpg](https://steemitimages.com/DQmemD8GF5W6Dh4gsS4fKAoLJ4Qq9wUGHMNzCR45BAbpizV/bild12.jpg)\n Toluene and water seperated.\n\n==============================================================================\n\n Now the crystals were purified by dissolving them in a minimal amount of boiling isopropylalcohol which is standing in a hot water bath, when they have all dissolved put a watch glass over the top of the erlenmyer and let them cool to room temperature; then put them in the deep freezer and vacuum filtrate them over a buchner filter and let them dry again.\n![bild13.jpg](https://steemitimages.com/DQmZJAVYxyiso3a7x49i4XZtje3Qi12N3RiECFMSX78iP14/bild13.jpg)\n![bild14.jpg](https://steemitimages.com/DQmcRhh9is4yenxSdZFnQVpoSQErDaQVa8vv2CPCFe1BZJf/bild14.jpg)\nBeaker with IPA standing in beaker with water. On the right the P2NP crystals.\n\n![bild15.jpg](https://steemitimages.com/DQmTtDvyaZXL5uCavPfRwS5jqqSi7Uc8XXwg68rcWS5QCLD/bild15.jpg)\n![bild16.jpg](https://steemitimages.com/DQma86bD6J1r3h7dVPMCnXL3B1xYtgfhNWxXynz8SKyQNcH/bild16.jpg)\nP2NP dissolved in boiling IPA.            Cooling down, you can see crystals forming\n\n\n![h1.jpg](https://steemitimages.com/DQmcDWBrPtYExYpZhJQzhvESfmXrjXz9JtEyaNb54UMbvzU/h1.jpg)\n![h2.jpg](https://steemitimages.com/DQmXhJu28irCN27Cz6PsfKo6b7rFsYkQQkyRHUoaHskxpiP/h2.jpg)\n![h3.jpg](https://steemitimages.com/DQmNWz3wHuQcDzw2yTHhFeLk3FpbzWqbbswtCg7MeyEJTka/h3.jpg)\n![h4.jpg](https://steemitimages.com/DQmNQyiiLAZkDkjRdy2jk9oEGaCtWn5SY77A4gvwN8krEaW/h4.jpg)\nHere you can see the crystals forming while cooling down, in the buchner filter the crystals were washed with water.  \nFrom the 14,03g of P2NP which SWIM started with 13,7g of P2NP was left over after the recrystalization/purification step. \n\n==============================================================================\n\n Now it is time (by the mean time the P2NP is dry again ;-) ) to do the aminated reduction of the P2NP to amphetamine.freebase.  \nThis was first tested with 3,5g of P2NP:  \nYou will need 5g Al foil cut it into 1 (2,5cm) squares and then fold them up to nuggets and you should wrap them up so tight that you can only still press them a little with your fingers.\n\n![g1.jpg](https://steemitimages.com/DQmPMTpQej9yE623D1qRfroNvzeccKSZt8NukN62vRP8VpK/g1.jpg)\nThis is the reflux setup that SWIM will be using. \n![g2.jpg](https://steemitimages.com/DQmPEHgHce3wE1FdeUtzt8T8S7x9eoMmqDmAQM37xFTWaSs/g2.jpg)\n Close up and methanol added which had 70mg of HgCl2 dissolved in it\n\nAs sayd above at the picture you will need a solvent like methanol and you dissolve HgCl2 inside the solvent and add it to the Aluminium make sure the aluminium is not too fine else a very heavy reaction will occur with the possibilty that mercury and hydrochloric acid, boiling methanol and hot aluminium will cover you like a vulcano. The HgCl2 can also be substituted by other Hg salts like Hg(NO3)2. \n\n==============================================================================\n\nAfter 10min average the Al will start to evolve hydrogen gas, depending on thickness of the foil. If you use thin foil wrap it up 3-4 layers before cuting squares out of it else it will react too heavily. \n\n![g3.jpg](https://steemitimages.com/DQmNy4TZMhHs8CPqQAHK8j4eH12tgAzRVcwRx8qhfjZ6u2g/g3.jpg)\nThe methanol will become gray/blue, and the aluminium will become less shiny. \n\nOn for hand you should make a solution of your P2NP that will be added to the mixture later on. The solvent used was isopropylalcohol and glacial acetic acid, in a ratio:\n\n 40ml IPA; 60ml GAA; 3,5g P2NP\n\nYou might need to heat it up because the P2NP will not dissolve easily at room temperature.\n\n==============================================================================\n\n![g4.jpg](https://steemitimages.com/DQmbLq3Bty1V6SQs4bzVPSZ67iJ42TX7v7AosPnvhoDGag1/g4.jpg)\nThe reaction will heat up and when there are dark spots on the Al and there is hydrogen gas bubbling of it you can add all the P2NP solution at once to the Al+MeOH+HgCl2.  \n\n![g5.jpg](https://steemitimages.com/DQmVFXu6yscbvUpnJrFRF2hNfb8A8998fwtErZB4L8WEDVH/g5.jpg)\nA little later in the progress, the mixture gets darker and heats up even more to a mild reflux\n\n==============================================================================\n\n![g6.jpg](https://steemitimages.com/DQmST8fPyfDCUWdGBQp8DTuQox1j9wXzVMEanmckUeqxBkv/g6.jpg)\nBy now the mixture is dark and the aluminium is dissolving slowely, you can notice small shiny pieces of aluminium floating around, extra heat is applied here because the Al was so big that it reacted not fast enough, but hey better slow reaction than a volcano, right.  \n\n![g7.jpg](https://steemitimages.com/DQmQDdzBZFureDPSd12EWsghqDJ1M5bkG58BaUGGw7hx1bS/g7.jpg)\nNow when almost all the Al has dissolved add 200ml of cold water to the mixture to cool it down. Then basify it to pH 12 with 50g of NaOH dissolved in 150ml water. All the remaining Al will now react with the NaOH and form hydrogen gas and the mixture will heat up but not to a boil, that wouldn t matter though. \n\n==============================================================================\n\n![a1.jpg](https://steemitimages.com/DQmWbYm97hyWrNhfPcTBoiwtn6kSf4jSQNPArHguycQZpRn/a1.jpg)\n![a2.jpg](https://steemitimages.com/DQmPcYpn4CxJKEJopREhCfBMd7GjZynTqqDof9DEM7UFNxZ/a2.jpg)\n\nAfter all the washed this was collected in total.   Anhydrous magnesiumsulfate was added to suck up the water in their molecules and thus drying the ether and your product.  \nNow you only have to wait 12 hours to let the MgSO4 do it s work, filtrate it and then you can let the ether evaporate off at room temperature or with the help of a warm lamp. NOT AN OPEN FLAME!!! Ether is very inflammable.  \nAll the ether was evaporated off and 50ml anhydrous IPA was added to the amphetamine.freebase. Then to anhydrous IPA 98% sulfuric acid was added calculate how many mol amphetamine freebase you ve got and then take 90% of that and calculate how many mols of H2SO4 that represents and add that to 15ml of anhydrous IPA. Now drip H2SO4+IPA mix into the freebase which is dissolved in the IPA. Here you can see the crystals forming after a few drops have been added. \n\n![a3.jpg](https://steemitimages.com/DQmZjSv8N85rewNkgPyBz7d5SY8bEJyZ22QMTfFab7k3C43/a3.jpg)\n\n==============================================================================\n\n![a4.jpg](https://steemitimages.com/DQmPqzjBQdNVy35DobzRoj3C6KotUE4Q6aUwUAVqq9PSCny/a4.jpg)\nGlass full of crystals. It wasn t that much though but it looks like it is full of crystals. \n\n![a5.jpg](https://steemitimages.com/DQmbVUDoXPGgBqMLc3dCAoz1cV49xdX4WegzN4G19cWy7qj/a5.jpg)\nFiltrate it.\n\n![a6.jpg](https://steemitimages.com/DQmdonBD7WVoyujnVuaarTms8xSKfkWTMLbGgLBn7UBArXG/a6.jpg)\nAnd finally pure amphetamine sulfate has been obtained this was around 180mg. When only starting with 3,5g P2NP, when you loose 1g in the filter that is a lot, with bigger amounts yields are better anyway. \n\n==============================================================================\n\nThis was a complete amphetamine synthese.\n\n~neverless",
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steemdelegated 18.239 SP to @neverless
2018/01/08 19:31:27
delegatorsteem
delegateeneverless
vesting shares29700.790909 VESTS
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neverlessupvoted (100.00%) @neverless / 8niwn18x
2018/01/08 14:02:48
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neverlessupdated options for 8niwn18x
2018/01/08 14:02:36
authorneverless
permlink8niwn18x
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neverlesspublished a new post: 8niwn18x
2018/01/08 14:02:36
parent author
parent permlinkdtube
authorneverless
permlink8niwn18x
titleGTA 5 MOD MENU MySick v1.0 (free download) 1.42
body<center><a href='https://d.tube/#!/v/neverless/8niwn18x'><img src='https://snap1.d.tube/ipfs/QmbrEUWco4PHV41p5KSL4eHShHuVfgDHC7HKcANbkeeQ6t'></a></center><hr> *DOESNT WORK FOR STEAM, ONLY FOR ROCKSTAR GAMES* - works offline and online - It's still undetected. And I haven't get banned yet. Navigate with the NumPad (open menu with *) Xenos64: https://mega.nz/#!8Fo2VDYK!Jg4RVZEZmb023VTS8_pIMDnsOmv1cxiBOyZ2_eLqIE4 MyStick.dll: https://mega.nz/#!cFQSRIbS!O-31uVM0JKh8MnpoO_1MpK2PRy2ZnF7uegYAr1bctLU Ban Protection: https://mega.nz/#!RRpX2SjT!cOvhL87xkod3gJIJHXyLMfXmrrSZ-BV7m36p6G0zHrw <hr><a href='https://d.tube/#!/v/neverless/8niwn18x'> ▶️ DTube</a><br /><a href='https://ipfs.io/ipfs/QmePViN5z9JUSxVWnFJJnJUBMWm5yeERn3C1JAGAJnMwB9'> ▶️ IPFS</a>
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      "permlink": "8niwn18x",
      "title": "GTA 5 MOD MENU MySick v1.0 (free download) 1.42",
      "body": "<center><a href='https://d.tube/#!/v/neverless/8niwn18x'><img src='https://snap1.d.tube/ipfs/QmbrEUWco4PHV41p5KSL4eHShHuVfgDHC7HKcANbkeeQ6t'></a></center><hr>\n\n*DOESNT WORK FOR STEAM, ONLY FOR ROCKSTAR GAMES*\n - works offline and online -\nIt's still undetected. And I haven't get banned yet. Navigate with the NumPad (open menu with *) \n\nXenos64: https://mega.nz/#!8Fo2VDYK!Jg4RVZEZmb023VTS8_pIMDnsOmv1cxiBOyZ2_eLqIE4\n\nMyStick.dll: https://mega.nz/#!cFQSRIbS!O-31uVM0JKh8MnpoO_1MpK2PRy2ZnF7uegYAr1bctLU\n\nBan Protection: https://mega.nz/#!RRpX2SjT!cOvhL87xkod3gJIJHXyLMfXmrrSZ-BV7m36p6G0zHrw\n\n<hr><a href='https://d.tube/#!/v/neverless/8niwn18x'> ▶️ DTube</a><br /><a href='https://ipfs.io/ipfs/QmePViN5z9JUSxVWnFJJnJUBMWm5yeERn3C1JAGAJnMwB9'> ▶️ IPFS</a>",
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}
asadullah101upvoted (100.00%) @neverless / 8jtei2gl
2018/01/08 13:50:36
voterasadullah101
authorneverless
permlink8jtei2gl
weight10000 (100.00%)
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neverlessupvoted (100.00%) @neverless / 8jtei2gl
2018/01/08 13:50:06
voterneverless
authorneverless
permlink8jtei2gl
weight10000 (100.00%)
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View Raw JSON Data
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neverlessupdated options for 8jtei2gl
2018/01/08 13:49:39
authorneverless
permlink8jtei2gl
max accepted payout1000000.000 SBD
percent steem dollars10000
allow votestrue
allow curation rewardstrue
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Transaction InfoBlock #18799435/Trx a856565b61a3fec00e1923f2fa753067902fc370
View Raw JSON Data
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neverlesspublished a new post: 8jtei2gl
2018/01/08 13:49:39
parent author
parent permlinkdtube
authorneverless
permlink8jtei2gl
titleDead by Daylight Bloodpoints Cheat 1.8.3
body<center><a href='https://d.tube/#!/v/neverless/8jtei2gl'><img src='https://snap1.d.tube/ipfs/Qmcu6GvjBuqyJ5GeXZfhjNiFrQ8BxknsAcK8qpwjL1oMBt'></a></center><hr> IMPORTANT: -Uncheck the option "Steam Cloud" on the Update page in the DbD settings!!!! - Undo everything after the cheating (delete firewall rule, repaste the AntiCheat folder)!! Cheat Engine: http://www.cheatengine.org/ Add me on Steam: https://steamcommunity.com/id/einfachmika3/ <hr><a href='https://d.tube/#!/v/neverless/8jtei2gl'> ▶️ DTube</a><br /><a href='https://ipfs.io/ipfs/QmU2MXQZYUKXAqUnAWq52q8vgUQhxbS9KdziUjufpN9VLZ'> ▶️ IPFS</a>
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View Raw JSON Data
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neverlessupvoted (100.00%) @acidyo / r9jw2pv6
2018/01/08 13:43:21
voterneverless
authoracidyo
permlinkr9jw2pv6
weight10000 (100.00%)
Transaction InfoBlock #18799310/Trx 3fa4c8731433ea5e6f244e07246cbe621f7c1e45
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}
neverlessupdated their account properties
2018/01/08 13:42:21
accountneverless
memo keySTM6SP5SfbFfyhYHYL6SYsgZgGF2mFtCL7wXRX92LRJHKrPX75787
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Transaction InfoBlock #18799290/Trx 277dc7ea948408070afb0e5f2acf96b874ef31ca
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neverlessupdated their account properties
2018/01/08 13:37:42
accountneverless
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Transaction InfoBlock #18799197/Trx ebbc6ae621c4761e168d528a3df336134260e25d
View Raw JSON Data
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neverlessupdated their account properties
2018/01/08 13:29:54
accountneverless
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Transaction InfoBlock #18799041/Trx e18d64cef2f3a1fbf9934acd51254b9289182a57
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2018/01/08 13:26:33
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required posting auths["neverless"]
idfollow
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Transaction InfoBlock #18798974/Trx d390e560afa938908d762b6c22f8543c0aa7827c
View Raw JSON Data
{
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neverlessupdated their account properties
2018/01/08 13:26:24
accountneverless
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Transaction InfoBlock #18798971/Trx 2f055a32b50a59ca46275d819396bf8fd36bc6a8
View Raw JSON Data
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neverlessupdated their account properties
2018/01/08 13:22:39
accountneverless
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Transaction InfoBlock #18798896/Trx e86b7167bf57f206e8230072184b7e01eb14a90c
View Raw JSON Data
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steemcreated a new account: @neverless
2018/01/08 13:19:24
fee0.500 STEEM
delegation57000.000000 VESTS
creatorsteem
new account nameneverless
owner{"weight_threshold":1,"account_auths":[],"key_auths":[["STM8Sfsr4ZcSG6uhzhv5BmTsvgoFhstrLvjEyq1BTiHWAP3RdjCB6",1]]}
active{"weight_threshold":1,"account_auths":[],"key_auths":[["STM71pZvEqxsDbrk2P9xioxhebCCjmS1L9b45kXuhXh7ZS8wxbJN2",1]]}
posting{"weight_threshold":1,"account_auths":[],"key_auths":[["STM7pTd2c2bNqt3ChyFMtik1EFYeEdU1L8QvGyHdVRMuwdaebvSoS",1]]}
memo keySTM6SP5SfbFfyhYHYL6SYsgZgGF2mFtCL7wXRX92LRJHKrPX75787
json metadata
extensions[]
Transaction InfoBlock #18798831/Trx bb342cc87bcf0ad5c0229ea95fdb8e67ee32f2e3
View Raw JSON Data
{
  "trx_id": "bb342cc87bcf0ad5c0229ea95fdb8e67ee32f2e3",
  "block": 18798831,
  "trx_in_block": 46,
  "op_in_trx": 0,
  "virtual_op": 0,
  "timestamp": "2018-01-08T13:19:24",
  "op": [
    "account_create_with_delegation",
    {
      "fee": "0.500 STEEM",
      "delegation": "57000.000000 VESTS",
      "creator": "steem",
      "new_account_name": "neverless",
      "owner": {
        "weight_threshold": 1,
        "account_auths": [],
        "key_auths": [
          [
            "STM8Sfsr4ZcSG6uhzhv5BmTsvgoFhstrLvjEyq1BTiHWAP3RdjCB6",
            1
          ]
        ]
      },
      "active": {
        "weight_threshold": 1,
        "account_auths": [],
        "key_auths": [
          [
            "STM71pZvEqxsDbrk2P9xioxhebCCjmS1L9b45kXuhXh7ZS8wxbJN2",
            1
          ]
        ]
      },
      "posting": {
        "weight_threshold": 1,
        "account_auths": [],
        "key_auths": [
          [
            "STM7pTd2c2bNqt3ChyFMtik1EFYeEdU1L8QvGyHdVRMuwdaebvSoS",
            1
          ]
        ]
      },
      "memo_key": "STM6SP5SfbFfyhYHYL6SYsgZgGF2mFtCL7wXRX92LRJHKrPX75787",
      "json_metadata": "",
      "extensions": []
    }
  ]
}

Account Metadata

POSTING JSON METADATA
profile{"profile_image":"http://fs1.directupload.net/images/180108/quwvj2te.jpg","cover_image":"http://fs1.directupload.net/images/180108/vzsrxknz.jpg","name":"NEVERLESS","about":"UNLEASHED CRIME","location":"127.0.0.1"}
JSON METADATA
profile{"profile_image":"http://fs1.directupload.net/images/180108/quwvj2te.jpg","cover_image":"http://fs1.directupload.net/images/180108/vzsrxknz.jpg","name":"NEVERLESS","about":"UNLEASHED CRIME","location":"127.0.0.1"}
{
  "posting_json_metadata": {
    "profile": {
      "profile_image": "http://fs1.directupload.net/images/180108/quwvj2te.jpg",
      "cover_image": "http://fs1.directupload.net/images/180108/vzsrxknz.jpg",
      "name": "NEVERLESS",
      "about": "UNLEASHED CRIME",
      "location": "127.0.0.1"
    }
  },
  "json_metadata": {
    "profile": {
      "profile_image": "http://fs1.directupload.net/images/180108/quwvj2te.jpg",
      "cover_image": "http://fs1.directupload.net/images/180108/vzsrxknz.jpg",
      "name": "NEVERLESS",
      "about": "UNLEASHED CRIME",
      "location": "127.0.0.1"
    }
  }
}

Auth Keys

Owner
Single Signature
Public Keys
STM6yEWYZVMk3LzBtWQurV5xPhxsjrYgoYUF6ZMz1EyD8wp92NxwJ1/1
Active
Single Signature
Public Keys
STM6ruFmuqHE6MWErpkVr9USS7BeJB7mQnaJC4DBaJu4rBhzXUSxS1/1
Posting
Single Signature
Public Keys
STM6vr4meB9H2SgW1CA4zsdGY243uxXr2jbWAus3x7aqYYtAz9JWe1/1
App Permissions
Memo
STM7isqcJrnEyaS8rjN7uPtptr1NCrhC3K1yC3XCehYqxkHY5crvb
{
  "owner": {
    "weight_threshold": 1,
    "account_auths": [],
    "key_auths": [
      [
        "STM6yEWYZVMk3LzBtWQurV5xPhxsjrYgoYUF6ZMz1EyD8wp92NxwJ",
        1
      ]
    ]
  },
  "active": {
    "weight_threshold": 1,
    "account_auths": [],
    "key_auths": [
      [
        "STM6ruFmuqHE6MWErpkVr9USS7BeJB7mQnaJC4DBaJu4rBhzXUSxS",
        1
      ]
    ]
  },
  "posting": {
    "weight_threshold": 1,
    "account_auths": [
      [
        "dtube.app",
        1
      ]
    ],
    "key_auths": [
      [
        "STM6vr4meB9H2SgW1CA4zsdGY243uxXr2jbWAus3x7aqYYtAz9JWe",
        1
      ]
    ]
  },
  "memo": "STM7isqcJrnEyaS8rjN7uPtptr1NCrhC3K1yC3XCehYqxkHY5crvb"
}

Witness Votes

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No active witness votes.
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