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      "title": "Rare disseminated elements -part1-",
      "body": "the earth's crust is made up of dozens of chemical elements, only fifteen are fairly widespread and are found in almost all rocks, as for the others, they are rarer.\nSome of these constitute large concentrations in the form of ores. The others, such as gold and platinum, the proportion of which in the crust of the earth is minimal, give almost imperceptible parcels of native metal and very rarely larger nuggets. However rare they are, they are found in the state of independent minerals, sometimes invisible to the naked eye, but always clean. There are also scarce elements which do not constitute separate minerals. Their compounds are found dissolved in others, more common as salt and sugar are in water, without knowing whether it is pure or not.\nThe chemical elements have for a long time wandered through molten masses and solutions, before meeting in rocks and veins in the state of stable combinations. during their travels they have undergone many transformations, only those who are very alike make the whole trip side by side.\nPlus grande est la similitude des propriétés de deux éléments, plus il est difficile de trouver une réaction chimique qui les dissocie. il y a des éléments rares qui, au lieu de se dégager sous l'aspect de minéraux à part, se dispersent dans de nombreux minéraux composés d'autres éléments; c'est pourquoi on les appelle les éléments disséminés.\nhttps://cdn.pixabay.com/photo/2014/05/16/16/06/pyrite-345637_960_720.jpg\n[Pixabay](https://pixabay.com/fr/photos/pyrite-pyrites-min%C3%A9raux-sulfure-345637/)\n\nWhat exactly? they are not spoken of in everyday life, nor even at school, although the development of technology makes their use more and more common. It is gallium, indium, thallium, cadmium, germanium, selenium, tellurium, rhenium, rubidium, radium, scandium, hafnium. We have only cited the most typical, we could extend the list further if necessary.\n\n- Let's take a look at where and in what state these elements are found in nature, how man has learned to detect them in other minerals and to use them. \nA yellow-brown stone, the fractures of which often present brilliant facets, absolutely regular, it is quite heavy, but hardly has the appearance of an ore, although it is one. It is blende or sphalerite.\nhttps://cdn.pixabay.com/photo/2015/02/20/11/19/mineral-643082_960_720.jpg\n[Pixabay](https://pixabay.com/fr/photos/min%C3%A9rale-nature-cristal-sphal%C3%A9rite-643082/)\nThe simplicity of the blende is fictitious, if the given sample is yellow-brown, others may be brown, dark brown, blackish, even black with a completely metallic luster.\nThe dark color of the blende is due to the iron sulphide dissolved in its mass: that which does not contain it is almost colorless, greenish or light yellow. The more iron there is, the darker the blende, so the color here is a sure indication of iron. X-ray examination of the interior structure of the blende reveals that the particles of zinc and sulfur are arranged therein such that each atom of zinc is surrounded by four atoms of sulfur, and vice versa.\nIn the blende we meet cadmium, gallium, indium, thallium, germanium .... zinc is, as we see, a very welcoming host. But sulfur is also capable, although to a lesser extent, of harboring rare elements: selenium and tellurium.",
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      "title": "Rare disseminated elements -part1-",
      "body": "the earth's crust is made up of dozens of chemical elements, only fifteen are fairly widespread and are found in almost all rocks, as for the others, they are rarer.\nSome of these constitute large concentrations in the form of ores. The others, such as gold and platinum, the proportion of which in the crust of the earth is minimal, give almost imperceptible parcels of native metal and very rarely larger nuggets. However rare they are, they are found in the state of independent minerals, sometimes invisible to the naked eye, but always clean. There are also scarce elements which do not constitute separate minerals. Their compounds are found dissolved in others, more common as salt and sugar are in water, without knowing whether it is pure or not.\nThe chemical elements have for a long time wandered through molten masses and solutions, before meeting in rocks and veins in the state of stable combinations. during their travels they have undergone many transformations, only those who are very alike make the whole trip side by side.\nPlus grande est la similitude des propriétés de deux éléments, plus il est difficile de trouver une réaction chimique qui les dissocie. il y a des éléments rares qui, au lieu de se dégager sous l'aspect de minéraux à part, se dispersent dans de nombreux minéraux composés d'autres éléments; c'est pourquoi on les appelle les éléments disséminés.\nhttps://cdn.pixabay.com/photo/2014/05/16/16/06/pyrite-345637_960_720.jpg\n[Pixabay](https://pixabay.com/fr/photos/pyrite-pyrites-min%C3%A9raux-sulfure-345637/)\n\nWhat exactly? they are not spoken of in everyday life, nor even at school, although the development of technology makes their use more and more common. It is gallium, indium, thallium, cadmium, germanium, selenium, tellurium, rhenium, rubidium, radium, scandium, hafnium. We have only cited the most typical, we could extend the list further if necessary.\n\n- Let's take a look at where and in what state these elements are found in nature, how man has learned to detect them in other minerals and to use them. \nA yellow-brown stone, the fractures of which often present brilliant facets, absolutely regular, it is quite heavy, but hardly has the appearance of an ore, although it is one. It is blende or sphalerite.\nhttps://cdn.pixabay.com/photo/2015/02/20/11/19/mineral-643082_960_720.jpg\n[Pixabay](https://pixabay.com/fr/photos/min%C3%A9rale-nature-cristal-sphal%C3%A9rite-643082/)\nThe simplicity of the blende is fictitious, if the given sample is yellow-brown, others may be brown, dark brown, blackish, even black with a completely metallic luster.\nThe dark color of the blende is due to the iron sulphide dissolved in its mass: that which does not contain it is almost colorless, greenish or light yellow. The more iron there is, the darker the blende, so the color here is a sure indication of iron. X-ray examination of the interior structure of the blende reveals that the particles of zinc and sulfur are arranged therein such that each atom of zinc is surrounded by four atoms of sulfur, and vice versa.\nIn the blende we meet cadmium, gallium, indium, thallium, germanium .... zinc is, as we see, a very welcoming host. But sulfur is also capable, although to a lesser extent, of harboring rare elements: selenium and tellurium.",
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      "title": "Rare disseminated elements -part1-",
      "body": "the earth's crust is made up of dozens of chemical elements, only fifteen are fairly widespread and are found in almost all rocks, as for the others, they are rarer.\nSome of these constitute large concentrations in the form of ores. The others, such as gold and platinum, the proportion of which in the crust of the earth is minimal, give almost imperceptible parcels of native metal and very rarely larger nuggets. However rare they are, they are found in the state of independent minerals, sometimes invisible to the naked eye, but always clean. There are also scarce elements which do not constitute separate minerals. Their compounds are found dissolved in others, more common as salt and sugar are in water, without knowing whether it is pure or not.\nThe chemical elements have for a long time wandered through molten masses and solutions, before meeting in rocks and veins in the state of stable combinations. during their travels they have undergone many transformations, only those who are very alike make the whole trip side by side.\nPlus grande est la similitude des propriétés de deux éléments, plus il est difficile de trouver une réaction chimique qui les dissocie. il y a des éléments rares qui, au lieu de se dégager sous l'aspect de minéraux à part, se dispersent dans de nombreux minéraux composés d'autres éléments; c'est pourquoi on les appelle les éléments disséminés.\nhttps://cdn.pixabay.com/photo/2014/05/16/16/06/pyrite-345637_960_720.jpg\n[Pixabay](https://pixabay.com/fr/photos/pyrite-pyrites-min%C3%A9raux-sulfure-345637/)\n\nWhat exactly? they are not spoken of in everyday life, nor even at school, although the development of technology makes their use more and more common. It is gallium, indium, thallium, cadmium, germanium, selenium, tellurium, rhenium, rubidium, radium, scandium, hafnium. We have only cited the most typical, we could extend the list further if necessary.\n\n- Let's take a look at where and in what state these elements are found in nature, how man has learned to detect them in other minerals and to use them. \nA yellow-brown stone, the fractures of which often present brilliant facets, absolutely regular, it is quite heavy, but hardly has the appearance of an ore, although it is one. It is blende or sphalerite.\nhttps://cdn.pixabay.com/photo/2015/02/20/11/19/mineral-643082_960_720.jpg\n[Pixabay](https://pixabay.com/fr/photos/min%C3%A9rale-nature-cristal-sphal%C3%A9rite-643082/)\nThe simplicity of the blende is fictitious, if the given sample is yellow-brown, others may be brown, dark brown, blackish, even black with a completely metallic luster.\nThe dark color of the blende is due to the iron sulphide dissolved in its mass: that which does not contain it is almost colorless, greenish or light yellow. The more iron there is, the darker the blende, so the color here is a sure indication of iron. X-ray examination of the interior structure of the blende reveals that the particles of zinc and sulfur are arranged therein such that each atom of zinc is surrounded by four atoms of sulfur, and vice versa.\nIn the blende we meet cadmium, gallium, indium, thallium, germanium .... zinc is, as we see, a very welcoming host. But sulfur is also capable, although to a lesser extent, of harboring rare elements: selenium and tellurium.",
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      "title": "Portland cement manufacturing process",
      "body": "Cement is a mixture of clay and limestone which is ground together and heated to a temperature of 1450 ° C, to obtain a powder with coherent properties which hardens in the presence of water on complex physico-chemical processes.\nCement = 80 percent limestone + 20 percent clay.\nhttps://cdn.pixabay.com/photo/2015/03/03/04/59/construction-656922_960_720.jpg\n[Pixabay](https://pixabay.com/fr/photos/la-construction-en-b%C3%A9ton-m%C3%A9lange-656922/)\n\nThe stages of portland cement production:\n-\n\n1)Extraction and crushing:\nThe limestone is extracted from mines which are often near the cement plant, while the clay is extracted using mechanical machines and transported to the cement plant.\nBefore using the extracted raw material, the crushing process takes place on the extraction site itself to reduce the particle size of limestone and clay to 50 nm.\n\n![image.png](https://cdn.steemitimages.com/DQmYpFMtu9CSoVcGYuo8tmPBAsCc3nr1X5mQ2Hc8kddge2w/image.png)\n[Pixabay](https://pixabay.com/fr/photos/carri%C3%A8re-machine-gravier-sable-4430879/)\n\n2)Preparation of vintage:\nAfter crushing the raw material (Clay and limestone) and reducing its particle size, a mixture of 80% limestone and 20% clay is prepared by grinding them together to obtain a powder with a particle size less than 200 micrometers.\n- vintage composition:\nCalcium carbonate CaCO3: from 77 to 83 percent.\nClay:\nSilica SiO2: 13 to 14 percent.\nAlumina Al2O3: from 02 to 04 percent.\nFerric oxide: 1.5 to 05 percent.\n\n3)Cooking:\nThe raw obtained from the previous process is placed in a rotary oven whose length varies between 70 to 120m and 05m in diameter. Inside the oven, there is an inclined tube (03 to 04 degrees from the horizontal) which rotates on itself from 02 to 03 rpm.\nThe cru advances and slides inside the internal walls of the oven which are covered by brick. The raw begins to agglomerate at a temperature of 1300 ° C, until the temperature reaches 1450 ° C, we get grains with a diameter of 0.5 to 04 cm called Clinker. The clinker cools quickly when it comes out of the oven to a temperature between 50 and 250 degrees Celsius to avoid strong crystallization.\n- Thermogravimetric analysis:\nat T = 100 ° C: evaporation of free water.\na T = 500 ° C: Departure of chemically bound water.\nat T = 800 to 1000 ° C: Dissociation of limestone:\n\nCaCO3 ====== CaO + CO2\n-\na T = 1000 at 1450 ° C: Reaction between CaO and the clay elements (SiO2, Al2O3, Fe2O3).\n\nCement notions:\n-\nCalcium oxide CaO == C\nSilicon oxide Si2O3 == S\nAlumina oxide Al2O3 == A\nFerric oxide == F\n\n- At the start of the fusion, the oxides combine to form:\nHydraulic silicates:\n3CaO.SiO2 ==== C3S (50 to 70 percent of the clinker)\n2CaO.SiO2 ==== C2S (10 to 30 percent of the clinker)\nHydraulic aluminates:\n3CaO.Al2O3 == C3A (02 to 15 percent of the clinker)\n4CaO.Al2O3.Fe2O3 == C4AF (5 to 15 percent of the clinker)\n\n4)Grinding:\nSince the diameter of the clinker grains is somewhat large when it comes out of the oven, it is ground to a size less than 80 picometers, after the addition of gypsum (CaSO4.2H2O) and other additions. This is called Portland cement.\nClinker + gypsum ===== grinding ==== portland cement.\n\n-----------------------------------------------------------------------------------------------------------------------------------\n\nHydration, setting and hardening:\n-\nHydration and setting:\n- The hydration process begins when adding water to the clinker, the properties of the paste obtained change over time with an increase in viscosity and heat generation. But before that, that is to say when the time has not advanced much, the dough is soft, which allows us to form it to obtain the desired shape.\nWhen the mixture hardens and the viscosity begins to increase, it is said to set.\n- Several factors affect this process:\nThe more advanced the grinding process, the shorter the setting time.\nThe setting stops at a temperature of 0 ° C, and the higher the temperature, the faster the setting:\nat 02 ° C: 6 p.m.\nat 2 ° C: 3h30min\nat 35 ° C: 30min\n\nIn addition, the setting slows down if there is an excess of water or if the water contains organic matter.\n\nHardening:\n- This stage occurs after setting, and it can last from 28 days to several months, during which the mechanical strength of the cement will continue to increase.\n\nUse of additions in the manufacture of cement:\n-\nCement production is a very expensive and polluting process that requires large amounts of water. Consequently, mineral additions are added to facilitate the production process and obtain a better quality of the product and also to reduce pollution and the cost of production.\n\n1)Technical advantages:\nThe additions reduce the need for water, thus improving the resistance to chemical attack and the mechanical resistance of the product (Example: resistance to cracking).\n\n![image.png](https://cdn.steemitimages.com/DQmTekMK3PKKvv8nPdf5Gofs2FyoFkqBdFkdACLeJtw1y18/image.png)\n[Pixabay](https://pixabay.com/fr/photos/le-crack-mur-b%C3%A9ton-texture-pierre-695010/)\n\n2)Ecological advantages:\nLarge amounts of carbon dioxide CO2 are emitted during the cement production process (for 1 ton of cement === 1 ton of CO2 emitted), therefore, mineral additions are added to reduce these emissions.\n\n![image.png](https://cdn.steemitimages.com/DQmcN3rNWxcb7VYGjUfeyv28HfbJ2xXgXqo1He7BuDv4PdT/image.png)\n[Pixabay](https://pixabay.com/fr/photos/la-pollution-usine-l-industrie-2575166/)\n\n3)Economic advantages:\nCement production consumes a lot of energy and therefore a high cost, and therefore additives are added to reduce energy needs and production costs.\n\n- Examples of some mineral additions:\n\n- Pouzzolan:\nA silicon rock of volcanic origin, gives birth to new compounds which are stable, sparingly soluble in water, weakly agglomerated.\n\n- Silica smoke:\nA byproduct of silicon manufacturing,\nAdvantage: make a very reactive product.\n\n\n\n\n\nSources:\n[Ciment Portland — Wikipédia](https://fr.wikipedia.org/wiki/Ciment_Portland)\n[Fabrication du ciment | lafarge.fr](https://www.lafarge.fr/fabrication-du-ciment)\n[Fabrication du ciment. Processus de fabrication du ciment ](https://www.febelcem.be/fr/ciment-applications/fabrication-du-ciment/)\n[Clinker — Wikipédia](https://fr.wikipedia.org/wiki/Clinker)\n[Béton à une faible teneur en clinker](https://www.cbr.be/fr/beton-faible-en-clinker)\n[Liant hydraulique — Wikipédia](https://fr.wikipedia.org/wiki/Liant_hydraulique)\n[CIMENT, Prise et durcissement du ciment - Encyclopædia](https://www.universalis.fr/encyclopedie/ciment/3-prise-et-durcissement-du-ciment/)\n[Etude physicochimique du ciment ](https://www.memoireonline.com/02/13/7021/m_Etude-physicochimique-du-ciment0.html)",
      "json_metadata": "{\"tags\":[\"steemstem\",\"science\",\"engineering\",\"chemistry\",\"life\"],\"image\":[\"https://cdn.pixabay.com/photo/2015/03/03/04/59/construction-656922_960_720.jpg\",\"https://cdn.steemitimages.com/DQmYpFMtu9CSoVcGYuo8tmPBAsCc3nr1X5mQ2Hc8kddge2w/image.png\",\"https://cdn.steemitimages.com/DQmTekMK3PKKvv8nPdf5Gofs2FyoFkqBdFkdACLeJtw1y18/image.png\",\"https://cdn.steemitimages.com/DQmcN3rNWxcb7VYGjUfeyv28HfbJ2xXgXqo1He7BuDv4PdT/image.png\"],\"links\":[\"https://pixabay.com/fr/photos/la-construction-en-b%C3%A9ton-m%C3%A9lange-656922/\",\"https://pixabay.com/fr/photos/carri%C3%A8re-machine-gravier-sable-4430879/\",\"https://pixabay.com/fr/photos/le-crack-mur-b%C3%A9ton-texture-pierre-695010/\",\"https://pixabay.com/fr/photos/la-pollution-usine-l-industrie-2575166/\",\"https://fr.wikipedia.org/wiki/Ciment_Portland\",\"https://www.lafarge.fr/fabrication-du-ciment\",\"https://www.febelcem.be/fr/ciment-applications/fabrication-du-ciment/\",\"https://fr.wikipedia.org/wiki/Clinker\",\"https://www.cbr.be/fr/beton-faible-en-clinker\",\"https://fr.wikipedia.org/wiki/Liant_hydraulique\",\"https://www.universalis.fr/encyclopedie/ciment/3-prise-et-durcissement-du-ciment/\",\"https://www.memoireonline.com/02/13/7021/m_Etude-physicochimique-du-ciment0.html\"],\"app\":\"steemit/0.2\",\"format\":\"markdown\"}"
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